22140-50-7Relevant academic research and scientific papers
Substituent Effects in the Solvolysis of p-(2-Substituted Cyclopropyl)-α-Methylbenzyl Chlorides
Kusuyama, Yoshiaki,Kubo, Takako,Iyo, Masami,Kagosaku, Tamami,Tokami, Kenjiro
, p. 2954 - 2960 (2007/10/02)
The solvolysis rates of p-(cis- or trans-2-substituted cyclopropyl)-α-methylbenzyl chlorides including electron-donating and electron-attracting substituents relative to a hydrogen substituent were measured in 80percent aqueous acetone.The trans isomers w
The Generation of CF and an Investigation of the Products of Its Reaction with Alkenes
Rahman, M.,McKee, Michael L.,Shevlin, Philip B.
, p. 6296 - 6299 (2007/10/02)
The reaction of arc generated carbon atoms with CF4 at 77 K in the presence of alkene trapping agents results in the formation of fluorocyclopropanes and 1,1-difluoroalkanes.The fluorocyclopropanes are postulated to arise by addition of CF to the double bond generating a cyclopropyl radical which abstracts H.CF adds stereospecifically to olefins and gives both cis and trans fluorocyclopropanes with the trans generally predominating.The 1,1-difluoroalkanes are postulated to be the result of a 3CF2 reaction.In the presence of oxygen, the CF is oxidized to CO2, and the 3CF2 gives carbonyl fluoride.
