221468-00-4

Basic information

• Product Name: (2S,5S,2'S,5'S)-5'-Benzyloxymethyl-octahydro-[2,2']bifuranyl-5-carbaldehyde
• Synonyms: (2S,5S,2'S,5'S)-5'-Benzyloxymethyl-octahydro-[2,2']bifuranyl-5-carbaldehyde
• CAS NO: 221468-00-4
• Molecular Weight: 290.359
• Mol File: 221468-00-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,5S,2'S,5'S)-5'-Benzyloxymethyl-octahydro-[2,2']bifuranyl-5-carbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,5S,2'S,5'S)-5'-Benzyloxymethyl-octahydro-[2,2']bifuranyl-5-carbaldehyde(221468-00-4)
• EPA Substance Registry System: (2S,5S,2'S,5'S)-5'-Benzyloxymethyl-octahydro-[2,2']bifuranyl-5-carbaldehyde(221468-00-4)

Safety Data

• Hazardous Substances Data: 221468-00-4(Hazardous Substances Data)

Upstream product

• 221467-95-4 (5S,6S)-5,6-dihydroxydeca-1,9-diene 
• 174645-23-9 (2S,5S,6S,9S)-2,5;6,9-diepoxydecane-1,10-diol 
• 100-39-0 benzyl bromide 
• 39139-91-8 trans-1,5,9-decatriene 
• 221468-58-2 (2S,5S,6S,9S)-1-benzyloxy-2,5;6,9-diepoxy-1-decanol 

Downstream Products

• 221468-04-8 (2S,5S,6S,9S,10S)-1-benzyloxy-2,5;6,9-diepoxy-10-tetracosanol 
• 221468-61-7 (2S,5S,6S,9S,10S)-1-benzyloxy-2,5;6,9-diepoxy-10-(methoxymethoxy)tetracosane 

Relevant articles and documents

The synthesis of asimilobin and the correction of its tetrahydrofuran segment's configuration

A highly efficient synthetic method for the trans/threo/trans- bis- tetrahydrofuran (THF) ring building block was established. The title compound was synthesized in thirteen steps from trans-1,4-dichloro-2-butene via a convergent route with a Wittig reaction as the key step. The absolute configuration of the THF segment of naturally occurring asimilobin should be corrected.