221469-91-6Relevant academic research and scientific papers
A Novel Synthesis of Highly Branched-Alkyl Aryl Ketones Using the Conjugate Addition of the Gilman Lithio Cuprate to β-Methylthio-α,β-unsaturated Ketones: Abnormal Reactivity of the Intermediary Enolates toward Molecular Oxygen
Arai, Takayuki,Akazome, Motohiro,Ogura, Katsuyuki
, p. 107 - 108 (2007/10/03)
In order to synthesize highly branched-alkyl aryl ketones, 1-(methylthio)-1-alken-2-yl phenyl ketones were subjected to the reaction with lithium dialkylcuprate. The high reactivity of an intermediary enolate toward molecular oxygen was found to give α-hy
