22170-24-7Relevant academic research and scientific papers
Mechanism of the transition-metal-catalyzed mutarotation reaction of N-(p-chlorophenyl)-β-D-glucopyranosylamine in methanol
Smiataczowa, Kazimiera,Kosmalski, Jaroslaw,Widernik, Teresa,Warnke, Zygmunt
, p. 969 - 975 (2007/10/03)
Rate constants for the mutarotation reaction of N-(p-chlorophenyl)-β-D-glucopyranosylamine (NGlc) in methanol have been determined in the presence of transition metal chlorides (MCl2), at 25°C. The activity of the metal ions catalyzing the α-py
Kinetics of the hydrogen chloride/methanol-catalyzed mutarotation reaction of N-(p-chlorophenyl)-β-D-glucopyranosylamine
Smiataczowa
, p. 1513 - 1522 (2007/10/03)
The rate of hydrogen chloride-catalyzed mutarotation reaction of N-(p-chlorophenyl)-β-D-glucopyranosylamine has been studied polarimetrically in absolute methanol at 25°C. Depending on the HCI concentration, conversion of isomer β to isomer α has been fou
Kinetics and mechanism of acid catalysis in the mutarotation reaction of N-(p-chlorophenyl)-β-D-glucopyranosylamine in methanolic benzoate buffer solutions
Smiataczowa,Maj,Korewa
, p. 831 - 839 (2007/10/03)
Rate constants of the mutarotation reaction of N-(p-chlorophenyl)-β-D-glucopyranosylamine have been determined in methanolic benzoate buffer solutions of various benzoic acid/sodium benzoate molar concentration ratios, at 25°C. The measurements were repea
Dissociation Constants of Carboxylic Acids and Phenols in Methanol Determined by the Catalytic Method
Smiataczowa, K.,Wawrzynow, A.,Korewa, R.
, p. 1306 - 1314 (2007/10/02)
Catalytic constants, kc, have been determined for the weak acid-catalyzed mutarotation reaction of N-(p-chlorophenyl)-β-D-glucopyranosyloamine in methanol, at 25 deg C.The Broensted law of catalysis has been exploited for calculations of new di
Acid Catalysis in the Mutarotation of N-(p-Chlorophenyl)-β-D-glucopyranosylamine in Methanolic Medium
Smiataczowa, Kazimiera
, p. 1593 - 1598 (2007/10/02)
The relationship has been studied between the rate of mutarotation of N-(p-chlorophenyl)-β-D-glucopyranosylamine and the concentration of a variety of substituted benzoic acids in methanol at 25 deg C.Catalytic constants of these acids and of 2,6-dinitrop
