2219-57-0Relevant academic research and scientific papers
One-pot construction of aza-or oxa-bridged benzocycloheptanes from readily available 2,3-allenyl malonates or 2,3-allenols and o-iodobenzaldehyde or imine
Li, Qiankun,Jiang, Xinpeng,Fu, Chunling,Ma, Shengming
supporting information; experimental part, p. 466 - 469 (2011/04/15)
A Pd(OAc)2-catalyzed reaction of 2,3-alkadienyl malonates or 2,3-allenols with o-iodobenzaldehyde or its N-tosyl imine occurred smoothly in MeCN at 80 °C to form the oxa-or aza-bridged benzocycloheptane derivatives with important biological pot
