222020-89-5Relevant academic research and scientific papers
Efficient syntheses of optically active 2-arylalkanoic acids
Beaulieu, Christian,Spino, Claude
, p. 1637 - 1640 (1999)
A highly enantioselective synthesis of 2-axylpropanoic acid was achieved, using a new developed methodology of cuprate addition to chiral carbonates derived from menthone.
An iterative approach to three fragments of ionomycin
Spino, Claude,Allan, Martin
, p. 177 - 184 (2007/10/03)
The SN2′ displacement of menthone-derived allylic carbonates with cuprate reagents occurs with high diastereoselectivity. This method can be used in an iterative fashion to construct stereocenters bearing a 1,3-relationship in a carbon chain. E
