222172-06-7Relevant academic research and scientific papers
trans-C-glycosides from 8-oxabicyclo[3.2.1]oct-6-en-3-one - Synthesis of the C3-C13 segment of the phorboxazoles A and B
Wolbers, Peter,Martin,Hoffmann
, p. 1905 - 1914 (1999)
The enantiopure and fully resolved C3-C13 segment of the phorboxazoles A and B has been prepared in 14 steps in 24% overall yield starting from 8- oxabicyclo[3.2.1]oct-6-en-3-one. Key steps are the desymmetrization of the oxabicyclic ketone, the anomeric
