222172-07-8

Upstream product

• 222172-06-7 endo-3-(4-methoxybenzyl)-oxy-8-oxa-bicyclo<3.2.1>oct-6-ene 
• 89858-82-2 endo-8-oxabicyclo[3.2.1]oct-6-en-3-ol 
• 824-94-2 p-methoxybenzyl chloride 
• 40458-77-3 8-oxabicyclo[3.2.1]oct-6-en-3-one 

Downstream Products

• 246859-64-3 <(2R,4R)-6-methoxy-4-(4-methoxybenzyl)-oxy-tetrahydropyran-2-yl>-acetic acid methyl ester 

Relevant academic research and scientific papers

Versatile 8-oxabicyclo[3.2.1]oct-6-en-3-one: stereoselective methodology for generating C-glycosides, delta-valerolactones, and polyacetate segments.

[figure: see text] A new rearrangement of functionalized methoxy glycosides and a regioselective as well as stereoselective intramolecular Michael addition giving delta-valerolactones and C-glycosides are described. Applications to the synthesis of marine

trans-C-glycosides from 8-oxabicyclo[3.2.1]oct-6-en-3-one - Synthesis of the C3-C13 segment of the phorboxazoles A and B

The enantiopure and fully resolved C3-C13 segment of the phorboxazoles A and B has been prepared in 14 steps in 24% overall yield starting from 8- oxabicyclo[3.2.1]oct-6-en-3-one. Key steps are the desymmetrization of the oxabicyclic ketone, the anomeric