222417-79-0

Upstream product

• 253596-63-3 (2S,3S,4S,5S,6S)-3,4,5,6-Tetrakis-benzyloxy-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 756-79-6 dimethyl methane phosphonate 
• 57783-76-3 benzyl 2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 858352-14-4 benzyl 2,3,4-tri-O-benzyl-α-D-mannopyranuronic acid 
• 128478-99-9 methylphosphonic acid dimethyl ester; deprotonated form 

Downstream Products

• 253596-64-4 3-O-benzyl-5-deoxy-5-C-[benzyl 2,3,4-tri-O-benzyl-7-deoxy-α-D-manno-heptopyranosid-6-ulose-7(E)-ylidene]-1,2-O-isopropylidene-α-D-xylofuranose 
• 253596-65-5 3-O-benzyl-5-deoxy-5-C-[benzyl 2,3,4-tri-O-benzyl-7-deoxy-D-glycero-α-D-manno-heptopyranosid-7(E)-ylidene]-1,2-O-isopropylidene-α-D-xylofuranose 
• 537036-62-7 benzyl 2,3,4,6-tetra-O-benzyl-7,8-dideoxy-7(E)-eno-9,10:11,12-di-O-isopropylidene-D-gluco-α-D-manno-dodeca-1,5-pyranoside 
• 537036-61-6 benzyl 2,3,4-tri-O-benzyl-7,8-dideoxy-7(E)-eno-9,10:11,12-di-O-isopropylidene-D-gluco-α-D-manno-dodeca-1,5-pyranoside 
• 106445-56-1 benzyl 2,3,4-tri-O-benzyl-α-D-glycero-D-manno-heptopyranoside 
• 537036-60-5 benzyl 2,3,4-tri-O-benzyl-7(E)-dideoxy-7(E)-eno-9,10:11,12-di-O-isopropylidene-6-oxo-D-arabino-α-D-manno-dodeca-1,5-pyranoside 

Relevant academic research and scientific papers

Reaction of sugar phosphonates with sucrose aldehydes. Synthesis of higher analogs of sucrose

The Horner-Emmons reaction between sugar phosphonates Sug-C(O)CH2 P(O)(OMe)2 and aldehydes derived from sucrose afforded precursors of higher analogs of the general formula Sug-C(O)CH=CH-Suc. An example of the functionalization of th

Application of sugar phosphonates for the preparation of higher carbon monosaccharides

Reaction of sugar derived phosphonates [Sug-C(O)CH2P(O)(OMe)2] with sugar aldehydes (Sug'-CHO) provides the higher enones of the general formula Sug-C(O)CH=CH-Sug' with the trans configuration of the double bond. The phosphonate meth