222545-55-3

Upstream product

• 143088-61-3 (2S)-1-bromo-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropane 
• 149-30-4 2-Mercaptobenzothiazole 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 95514-03-7 (S)-3-(tert-butyl-diphenyl-silanyloxy)-2-methyl-propionic acid methyl ester 
• 95514-04-8 (R)-3-(tert-butyldiphenylsilyloxy)-2-methylpropan-1-ol 

Downstream Products

• 222545-56-4 (S)-3-(benzothiazol-2-yl)sulfanyl-1-tert-butyldiphenylsilyloxy-2-methylpropane 
• 222545-58-6 (3E,5E)-(R)-8-(tert-Butyl-diphenyl-silanyloxy)-3,7-dimethyl-octa-3,5-dien-1-ol 
• 222545-62-2 tert-Butyl-((3E,5E)-(R)-8-iodo-2,6-dimethyl-octa-3,5-dienyloxy)-diphenyl-silane 
• 222545-65-5 (1R,2R,4aS,8aS)-1-[(3E,5E)-(R)-8-(tert-Butyl-diphenyl-silanyloxy)-3,7-dimethyl-octa-3,5-dienyl]-2,5,5,8a-tetramethyl-decahydro-naphthalen-1-ol 

Relevant academic research and scientific papers

Natural product synthesis from (8aR)- and (8aS)-bicyclofarnesols: synthesis of (+)-wiedendiol A, (+)-norsesterterpene diene ester and (-)-subersic acid

Both enantiomers (8aR)-7 and (8aS)-7 of bicyclofarnesol were synthesized from the enzymatic resolution products (1R,4aR,8aR)-1,2,3,4,4a,5,6,7,8,8a-decahydro-5,5,8a-trimethyl-2-oxo-trans-naphthalene-1-methanol-2-ethylene acetal (8aR)-5 (98% ee) and acetate

Convergent synthesis of the putative biogenetic precursor of mycaperoxide B and a norsesterterpene triene isolated from an Australian sponge

The synthesis of enantiomerically pure norsesterterpene triene ester 1, extracted from an Australian marine sponge Latrunculia brevis, has been achieved by preparation of E,E-diene 3a via a Julia one-pot olefination and addition to 2,5,5,8a-tetramethyl-oc