222725-96-4Relevant academic research and scientific papers
Application of molybdenum bis(imido) complexes in ethylene dimerisation catalysis
Wright, William R. H.,Batsanov, Andrei S.,Messinis, Antonis M.,Howard, Judith A. K.,Tooze, Robert P.,Hanton, Martin J.,Dyer, Philip W.
, p. 5502 - 5511 (2012/05/20)
In combination with EtAlCl2 (Mo:Al = 1:15) the imido complexes [MoCl2(NR)(NR′)(dme)] (R = R′ = 2,6-Pri 2-C6H3 (1); R = 2,6-Pri 2-C6H3, R′ = Busu
Synthesis, characterisation and reactivity of the molybdenum(VI) dimethyl complex [Mo(NR)2Me2] (R = 2,6-Pri2C6H3)
Gibson, Vernon C.,Redshaw, Carl,Walker, Gary L. P.,Howard, Judith A. K.,Hoy, Vanessa J.,Cole, Jacqueline M.,Kuzmina, Lyudmila G.,De Silva, Dinali S.
, p. 161 - 165 (2007/10/03)
The reaction of [Mo(NR)2Cl2(dme)] (R = 2,6-Pri2C6H3, dme = 1,2-dimethoxyethane) with 2 equivalents of methylmagnesium bromide in diethyl ether afforded [Mo(NR)2Me2] 2 as a red crystalline solid in good yield. Treatment of 2 with the donor molecules tetrahydrofuran (thf), pyridine, PMe3, and PMe2Ph gave the five-coordinate adducts [Mo(NR)2Me2(L)] (L = PMe3 3, PMe2Ph 4, thf 5 or pyridine 6). Exposure of solutions of 2 to atmospheric dioxygen afforded the orange methoxide-bridged complex [{Mo(NR)2Me(μ-OMe)}2] 7. [{Mo(NBut)2-Me(μ-OMe)}n], 8 (n = 1 or 2) was obtained from the reaction of [{Mo(NBut)2Me2}2] 1 with dioxygen. The crystal structures of 2,4 and 7 have been determined.
