22276-37-5

Upstream product

• 84624-72-6 {(P(C₂H₅)3)2HPt(H)PtH(P(C₂H₅)3)2}⁽¹⁺⁾*B(C₆H₅)4^(1-)={(P(C₂H₅)3)2HPtHPtH(P(C₂H₅)3)2}{B(C₆H₅)4} 
• 101076-58-8 PtH(P(CH₂CH₃)3)3OH 
• 143-66-8 sodium tetraphenyl borate 
• 554-70-1 triethylphosphine 
• 81800-05-7 {(P(C₂H₅)3)2HPt(H)2Pt(P(C₂H₅)3)2}⁽¹⁺⁾*B(C₆H₅)4^(1-)={(P(C₂H₅)3)2HPt(H)2Pt(P(C₂H₅)3)2}{B(C₆H₅)4} 

Downstream Products

• 39045-37-9 tris(triethylphosphine)platinum⁽⁰⁾ 
• 1333-74-0 hydrogen 
• 22423-00-3 chlorotris(triethylphosphine)platinum(II) 
• 13965-02-1 cis-dichlorobis(triethylphosphine)platinum(II) 
• 96346-99-5 [PtCl₂H₂(P(CH₂CH₃)3)2] 
• 40895-04-3 cis,cis,trans-[PtH₂Cl₂(PEt₃)2] 

Relevant academic research and scientific papers

HYDROTHERMAL REACTIONS OF LACTIC ACID CATALYSED BY GROUP VIII METAL COMPLEXES

At 220-250 deg C, in the presence of + in aqueous solution, α-hydroxypropanoic acid (lactic acid) is converted into propanoic, propenoic, β-hydroxypropanoic, pyruvic and acetic acids.The reactions catalysed by + appear to be double bond hydration and hydrogenation, alcohol dehydration, transfer hydrogenation, decarbonylation and the water-gas shift reaction.Propenoic acid under similar conditions gives similar products.Attempts to catalyse the dehydrocarboxylation of lactic acid using PdCl2, , and were partially successful, although competing disproportionation gave a wide range of products.

Generation of reactive intermediates in the photochemistry of binuclear trihydridodiplatinum complexex

The photochemistry of the complexes trans-trans monohydrido-bridged [(PEt3)2HPt(μ-H)PtH(PEt3) 2][BPh4] (1) and trans-cis dihydrido-bridged [(PEt3)2HPt(μ-H)2Pt(PEt3) 2][BPh4] (2) is reported. Photolysis of 1 and 2 using 334-nm light occurs with good quantum yields to give trans-[PtH2(PEt3)2] (3a) and trans-[PtH(S)(PEt3)2]+ (4) (S = solvent, e.g. acetonitrile). Photoproducts 3a and 4 are highly reactive and undergo a multiplicity of reactions depending upon experimental conditions. Evidence of H2 elimination, photoinduced insertion of CO2 into the Pt-H bond of 3a, and abstraction of Cl from chlorocarbon solvents by 3a and 4 is reported.