22277-52-7Relevant academic research and scientific papers
P,N-bidentate phosphites with a chiral ketimine fragment, their application in enantioselective allylic substitution and comparison with phosphine analogues
Gavrilov, Konstantin,Tsarev, Vasily,Zheglov, Sergey,Korlyukov, Alexander,Antipin, Mikhail,Davankov, Vadim
, p. 1717 - 1723 (2007)
Novel chiral P,N-bidentate arylphosphites have been prepared by a one-step phosphorylation of appropriate hydroxy ketimines based on (R)-(+)-camphor. Metal chelate complexes [Rh(CO)(PN)Cl] and [Pd(PN)(allyl)]BF4 with the ligands were obtained a
STABILE ADDUKTE BEI DER CHLORIERUNG VON 2,6-DIMETHYLPHENYLPHOSPHITEN
Gloede, Joerg,Waschke, Regine
, p. 187 - 194 (2007/10/02)
PIII compounds of type 4 react with chlorine to give stable adducts.The phosphite 4a gives the chlorophosphonium chloride 6 and the chlorophosphites 4b and 4c give the chlorophosphoranes 8 and 10.Key words: Chlorophosphonium salts; trichloro-di
