22339-44-2Relevant academic research and scientific papers
Regioselective Radical Cyclization by Electrochemical Reduction Using an Arene Mediator. Environmentally Benign Method
Kurono, Nobuhito,Honda, Eiichi,Komatsu, Fumikazu,Orito, Kazuhiko,Tokuda, Masao
, p. 720 - 721 (2003)
Electrochemical reduction of 2-(but-3-enyl)-1-haloarenes in the presence of phenanthrene as a mediator generated the corresponding aryl radicals and gave cyclized products in good yields. Higher regio- and stereoselectivities than those of usual radical cyclization using AIBN-TBTH were achieved.
Regioselective synthesis of substituted 1-indanols, 2,3-dihydrobenzofurans and 2,3-dihydroindoles by electrochemical radical cyclization using an arene mediator
Kurono, Nobuhito,Honda, Eiichi,Komatsu, Fumikazu,Orito, Kazuhiko,Tokuda, Masao
, p. 1791 - 1801 (2007/10/03)
Electrochemical reduction of haloarenes carrying 2-(1-hydroxybut-3-enyl), 2-allyloxy or N-allyl-N-methylamino group in the presence of phenanthrene as a mediator generated the corresponding aryl radicals and gave the corresponding 5-exo cyclization produc
