2234-06-2

Basic information

• Product Name: dichlorodiphenoxytitanium
• Synonyms: dichlorodiphenoxytitanium;Dichlorobis(phenyloxy)titanium(IV);Diphenoxydichlorotitanium(IV)
• CAS NO: 2234-06-2
• Molecular Formula: C₁₂H₁₀Cl₂O₂Ti
• Molecular Weight: 304.9796
• EINECS: 218-777-1
• Mol File: 2234-06-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 181.8°Cat760mmHg
• Flash Point: 72.5°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 0.614mmHg at 25°C
• CAS DataBase Reference: dichlorodiphenoxytitanium(CAS DataBase Reference)
• NIST Chemistry Reference: dichlorodiphenoxytitanium(2234-06-2)
• EPA Substance Registry System: dichlorodiphenoxytitanium(2234-06-2)

Safety Data

• Hazardous Substances Data: 2234-06-2(Hazardous Substances Data)

Usage

InChI:InChI=1/2C6H6O.2ClH.Ti/c2*7-6-4-2-1-3-5-6;;;/h2*1-5,7H;2*1H;/q;;;;+2/p-2/r2C6H6O.Cl2Ti/c2*7-6-4-2-1-3-5-6;1-3-2/h2*1-5,7H;

Upstream product

• 7550-45-0 titanium tetrachloride 
• 36496-76-1 (cyclopentadienyl)TiCl(OPh)2 

Downstream Products

• 77659-99-5 (C₆H₅O)2Ti(S₂CN(CH(CH₃)2)2)2 
• 77660-02-7 (C₆H₅O)2Ti(S₂CN(CH(CH₃)2)(C₆H₁₁))2 
• 77660-01-6 (C₆H₅O)2Ti(S₂CN(CH₂CH₃)(C₆H₁₁))2 
• 77659-98-4 (C₆H₅O)2Ti(S₂CN(CH₂CH₃)2)2 
• 77660-00-5 (C₆H₅O)2Ti(S₂CN(CH₃)(C₆H₁₁))2 
• 77659-97-3 (C₆H₅O)2Ti(S₂CN(CH₃)2)2 
• 101050-05-9 (C₆H₅O)2TiCl₂(C₆H₅)2PCH₂CH₂P(C₆H₅)2 
• 101050-03-7 (C₆H₅O)2TiCl₂(CH₃)2PCH₂CH₂P(CH₃)2 
• 101050-06-0 (C₆H₅O)2TiCl₂(CH₃)2NCH₂CH₂N(CH₃)2 
• 101050-02-6 (C₆H₅O)2TiCl₂(P(CH₃)3)2 

Relevant articles and documents

Ligation Studies of Titanium-Phenoxide and -Dimethylamide Derivatives with Covalent Metal Halides: a Route to Binuclear Transition-metal Complexes

Convenient and high-yield syntheses for (Ti(cp)(OPh)3) and (Ti(cp)Cl(OPh)2) (cp=η-C5H5) are described.The donor characteristics of the mixed phenoxides (Ti(cp)n(OPh)(4-n)), n=0, 1, or 2, ((TiCl2(OPh)2)2), (Ti(cp)Cl(OPh)2), and of Ti(NMe2)4 have been investigated.Reactions with MCl3 (M=Ti, V, or Cr), VOCl3, MX4 (M=Ti, Zr, Hf, or Sn; X=Cl or Br), and MCl5 (M=Nb, Ta, or Mo) generally feature exchange of OPh and NMe2 groups with halide rather than complexation.In several instances, using appropriate reaction conditions, the solid adducts MX4Ti(NMe2)4 (M=Sn, X=CL or Br; M=Zr or Hf, X=Cl), SnCl4(Ti(cp)2(OPh)2), and ZrCl4Ti(OPh)4 have been isolated and fully characterised by analitycal and spectral data.