223482-03-9Relevant academic research and scientific papers
Carbonyllithium chemistry. Intramolecular conversion of an acyllithium via the utilization of an anionic 1,2-stannyl rearrangement
Iwamoto, Keiji,Chatani, Naoto,Murai, Shinji
, p. 171 - 175 (1999)
The reaction of α-stannylmethyllithium with CO (1 atm) generates the acyllithium that smoothly undergoes anionic 1,2-stannyl rearrangement at -78°C to give the enolate derivative of acyltin. The rearrangement of the stannyl group is much faster than that
