22352-62-1

Upstream product

• 22352-62-1 O¹,O²,O⁴,O⁶-Tetraacetyl-O³-(tetra-O-acetyl-α-D-galactopyranosyl)-ξ-D-glucopyranose 
• 108-24-7 acetic anhydride 
• 35106-01-5 3,4,6-tri-O-acetyl-1,2-O-<1-(exo-cyano)ethylidene>-α-D-glucopyranose 
• 99337-72-1 1,2,4,6-tetra-O-acetyl-3-O-trityl-β-D-glucopyranose 
• 27086-14-2 1,2,4,6-tetra-O-acetyl-β-D-glucopyranose 
• 604-69-3 β-D-glucose pentaacetate 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 40592-72-1 O³-α-D-Galactopyranosyl-D-glucose 

Downstream Products

• 22352-62-1 O¹,O²,O⁴,O⁶-Tetraacetyl-O³-(tetra-O-acetyl-ξ-D-galactopyranosyl)-ξ-D-mannopyranose 
• 85373-00-8 phenyl 3-O-α-D-glucopyranosyl-α-D-glucopyranoside 
• 85372-99-2 phenyl 2,4-di-O-acteyl-3-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-α-D-glucopyranoside 

Relevant academic research and scientific papers

The Synthesis of Active-Site Directed Inhibitors of Some β-Glucan Hydrolases

The 2,3-epoxypropyl, 3,4-epoxybutyl and 4,5-epoxypentyl β-glycosides of D-glucose, cellobiose and laminaribiose have been prepared.As well, the 4,5-epoxypentyl β-glycosides of cellotriose, laminaritriose and two other trisaccharides have been synthesized. 3,4-Epoxybutyl β-cellobioside has also been prepared with a 14C-label in the cellobiose residue.

THE EFFECT OF HIGH PRESSURE ON THE STEREOSPECIFICITY OF THE GLYCOSYLATION REACTION

At a pressure of 1,4 GPa and room temperature, the glycosylation of trityl ethers by 1,2-O-cyanoethylidene derivatives of sugars, and the polycondensation of the proper monomers in dichloromethane, proceed with absolute stereospecificity, giving rise to a