223690-15-1

Basic information

• Product Name: methyl 5-bromo-2-phenylpentanoate
• Synonyms: methyl 5-bromo-2-phenylpentanoate
• CAS NO: 223690-15-1
• Molecular Weight: 271.154
• Mol File: 223690-15-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 5-bromo-2-phenylpentanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 5-bromo-2-phenylpentanoate(223690-15-1)
• EPA Substance Registry System: methyl 5-bromo-2-phenylpentanoate(223690-15-1)

Safety Data

• Hazardous Substances Data: 223690-15-1(Hazardous Substances Data)

Upstream product

• 109-64-8 1,3-dibromo-propane 
• 101-41-7 benzeneacetic acid methyl ester 

Downstream Products

• 61604-86-2 (R)-2-phenyl-adipic acid 
• 17540-20-4 (S)-2-phenyl-adipic acid 
• 2628-88-8 2-phenyl-1,6-hexanedioic acid 

Relevant articles and documents

Donor-acceptor binary photocatalysis system illustrated by the intramolecular cyclization of a cyclopropanone acetal tethered to cyclohexen- 2-one

Irradiation of 2-[3-(2-methoxy-1-phenyl-2-TBDMSO-cyclopropyl)-propyl]- 2-cyclohexen-l-one (5) in the presence of Mg(ClO4)2 (1 mol equiv) and 9,10- dicyanoanthracene (DCA, 0.5 mol equiv) in acetonitrile formed methyl 5-oxo- 1-phenyldecahydro-l-naphthateneacetate (6) in 63% yield. When pyrene was adopted in place of DCA, the yield of 6 was 38%. The results indicate that the photocyclization of 5 induced by the SET can be catalyzed by both donor- and acceptor-type photocatalysts. Irradiation of a similar substrate, 4-(2- methoxy-1-phenyl-2-TBDMSO-cyclopropyl)butyl 2-naphthyl ketone (21), produced methyl 2-hydroxy-2-(2-naphthyl)-l-phenylcyclohexaneacetate (27) in 13% in the presence of p-dicyanobenzene (0.1 mol equiv) and 8% in its absence.