223692-97-5

Upstream product

• 100-39-0 benzyl bromide 
• 223692-96-4 (2S,3R,4S,6S)-2-allyl-6-[(tert-butyldiphenylsiloxy)methyl]tetrahydro-3-methyl-2H-pyran-4-ol 
• 261374-46-3 [[(2S,4S,5R,6S)-6-allyl-4-(benzyloxy)tetrahydro-5-methyl-2H-pyran-2-yl]methoxy]-tert-butyldiphenylsilane 

Downstream Products

• 223692-98-6 (2S,3R,4S,6S)-2-allyl-4-(benzyloxy)tetrahydro-3-methyl-6-[2-(phenylsulfonyl)ethyl]-2H-pyran 
• 223693-07-0 (1S,5S,7R,9R,13S,15S,16R)-15-(benzyloxy)-7-[(p-methoxybenzyl)oxy]-6,6,9,16-tetramethyl-3,10-dioxo-11-(phenylsulfonyl)-4,17-dioxabicyclo[11.3.1]heptadecane-5-carboxaldehyde 
• 223693-26-3 (1S,5S,7R,9R,13S,15S,16R)-15-(benzyloxy)-5-[(hydroxy)methyl]-7-[(p-methoxybenzyl)oxy]-6,6,9,16-tetramethyl-11-(phenylsulfonyl)-4,17-dioxabicyclo[11.3.1]heptadecane-3,10-dione 
• 223693-08-1 (1S,5S,7R,9R,13S,15S,16R)-15-(benzyloxy)-5-[(E)-2-iodovinyl]-7-[(p-methoxybenzyl)oxy]-6,6,9,16-tetramethyl-11-(phenylsulfonyl)-4,17-dioxabicyclo[11.3.1]heptadecane-3,10-dione 
• 223693-05-8 (2S,4S,5R,6S)-4-(benzyloxy)-6-[(4R,6R,8S)-9-(tert-butyldiphenylsiloxy)-8-hydroxy-6-[(p-methoxybenzyl)oxy]-4,7,7-trimethyl-3-oxo-2-(phenylsulfonyl)-3-nonyl]tetrahydro-3-methyl-2H-pyran-2-acetaldehyde 
• 223693-06-9 (1S,5S,7R,9R,13S,15S,16R)-15-(benzyloxy)-5-[(tert-butyldiphenylsiloxy)methyl]-7-[(p-methoxybenzyl)oxy]-6,6,9,16-tetramethyl-11-(phenylsulfonyl)-4,17-dioxabicyclo[11.3.1]heptadecane-3,10-dione 
• 223693-22-9 (4R,6R,8S)-1-[(2S,4S,5R,6S)-6-allyl-4-(benzyloxy)tetrahydro-5-methyl-2H-pyran-2-yl]-9-(tert-butyldiphenylsiloxy)-8-hydroxy-6-[(p-methoxybenzyl)oxy]-4,7,7-trimethyl-2-(phenylsulfonyl)-3-nonanone 
• 223693-28-5 (1S,4R,5R,7R,9R,13S,14S,15S)-4-hydroxy-9-[(E)-2-iodovinyl]-15-[[3-O-[4-O-(p-methoxybenzyl)-2,3-di-O-methyl-α-L-fucopyranosyl]-2,4-di-O-methyl-β-D-xylopyranosyl]oxy]-5,8,8,14-tetramethyl-10,17,18-trioxatricyclo[11.3.1.1^4,7]octadecane-3,11-dione 
• 223693-24-1 (2S,4S,5R,6S)-4-(benzyloxy)-6-[(4R,6R,8S)-9-(tert-butyldiphenylsiloxy)-8-hydroxy-6-[(p-methoxybenzyl)oxy]-4,7,7-trimethyl-3-oxo-2-(phenylsulfonyl)-3-nonyl]tetrahydro-3-methyl-2H-pyran-2-acetic acid 
• 223693-04-7 (4R,6R,8S)-1-[(2S,4S,5R,6S)-6-allyl-4-(benzyloxy)tetrahydro-5-methyl-2H-pyran-2-yl]-9-(tert-butyldiphenylsiloxy)-6-[(p-methoxybenzyl)oxy]-4,7,7-trimethyl-2-(phenylsulfonyl)-8-(triethylsiloxy)-3-nonanone 
• 223693-19-4 (4R,6R,8S)-1-((2S,4S,5R,6S)-6-Allyl-4-benzyloxy-5-methyl-tetrahydro-pyran-2-yl)-2-benzenesulfonyl-9-(tert-butyl-diphenyl-silanyloxy)-6-(4-methoxy-benzyloxy)-4,7,7-trimethyl-8-triethylsilanyloxy-nonan-3-ol 
• 261374-52-1 (1S,4R,5R_.7R,9S,13S,14R,15S)-15-(benzyloxy)-9-[(tert-butyldiphenylsiloxy)methyl]-4-hydroxy-5,8,8,14-tetramethyl-10,17,18-trioxatricyclo[11.3.1.1^4,7]octadecane-3,11-dione 
• 261374-51-0 (1S,5S,7R,9R,13S,15S,16R)-15-(benzyloxy)-5-[(tert-butyldiphenylsiloxy)methyl]-7-[(p-methoxybenzyl)oxy]-6,6,9,16-tetramethyl-4,17-dioxabicyclo[11.3.1]heptadecane-3,10,11-trione 
• 261374-49-6 (4R,6R,8S)-1-[(2S,4S,5R,6S)-6-allyl-4-(benzyloxy)tetrahydro-5-methyl-2H-pyran-2-yl]-9-(tert-butyldiphenylsiloxy)-6-[(p-methoxybenzyl)oxy]-4,7,7-trimethyl-8-(triethylsiloxy)-2,3-nonanedione 

Relevant academic research and scientific papers

Stereocontrolled elaboration of natural (-)-polycavernoside A, a powerfully toxic metabolite of the red alga Polycavernosa tsudai

A stereoselective total synthesis of natural levorotatory polycavernoside A (1) has been achieved. Initial investigations produced the properly activated disaccharide unit 18b via the conjoining of building blocks originating from L-fucose and D-xylose. T