223692-99-7

Upstream product

• 3282-30-2 pivaloyl chloride 
• 223693-13-8 (2R,4R)-6-(tert-Butyl-diphenyl-silanyloxy)-2,5,5-trimethyl-hexane-1,4-diol 
• 215317-64-9 (3R,5R)-5-(1-(tert-butyldiphenylsilyloxy)-2-methylpropan-2-yl)-3-methyldihydrofuran-2(3H)-one 

Downstream Products

• 223693-14-9 (2R,4R)-6-(tert-butyldiphenylsiloxy)-4-[(p-methoxybenzyl)oxy]-2,5,5-trimethylhexyl pivalate 
• 223693-00-3 (2R,4R)-5-formyl-4-[(p-methoxybenzyl)oxy]-2,5-dimethylhexyl pivalate 
• 223693-16-1 (2R,4R)-[(p-methoxybenzyl)oxy]-2,5,5-trimethyl-6-heptenyl pivalate 
• 223693-15-0 (2R,4R)-6-hydroxy-4-[(p-methoxybenzyl)oxy]-2,5,5-trimethylhexyl pivalate 
• 223693-01-4 (2R,4R,6S)-6,7-dihydroxy-4-[(p-methoxybenzyl)oxy]-2,5,5-trimethylheptyl pivalate 
• 261374-58-7 2,2-Dimethyl-propionic acid (2R,4R,6S)-7-(tert-butyl-diphenyl-silanyloxy)-6-hydroxy-4-(4-methoxy-benzyloxy)-2,5,5-trimethyl-heptyl ester 
• 223693-03-6 (2R,4R,6S)-7-(tert-butyldiphenylsiloxy)-4-[(p-methoxybenzyl)oxy]-2,5,5-trimethyl-6-(triethylsiloxy)heptanal 
• 223693-17-2 (2R,4R,6S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2,5,5-trimethyl-6-triethylsilanyloxy-heptan-1-ol 
• 223693-07-0 (1S,5S,7R,9R,13S,15S,16R)-15-(benzyloxy)-7-[(p-methoxybenzyl)oxy]-6,6,9,16-tetramethyl-3,10-dioxo-11-(phenylsulfonyl)-4,17-dioxabicyclo[11.3.1]heptadecane-5-carboxaldehyde 
• 223693-02-5 (2R,4R,6S)-7-(tert-butyldiphenylsiloxy)-4-[(p-methoxybenzyl)oxy]-2,5,5-trimethyl-6-(triethoxy)heptyl pivalate 
• 223693-26-3 (1S,5S,7R,9R,13S,15S,16R)-15-(benzyloxy)-5-[(hydroxy)methyl]-7-[(p-methoxybenzyl)oxy]-6,6,9,16-tetramethyl-11-(phenylsulfonyl)-4,17-dioxabicyclo[11.3.1]heptadecane-3,10-dione 
• 223693-08-1 (1S,5S,7R,9R,13S,15S,16R)-15-(benzyloxy)-5-[(E)-2-iodovinyl]-7-[(p-methoxybenzyl)oxy]-6,6,9,16-tetramethyl-11-(phenylsulfonyl)-4,17-dioxabicyclo[11.3.1]heptadecane-3,10-dione 
• 223693-05-8 (2S,4S,5R,6S)-4-(benzyloxy)-6-[(4R,6R,8S)-9-(tert-butyldiphenylsiloxy)-8-hydroxy-6-[(p-methoxybenzyl)oxy]-4,7,7-trimethyl-3-oxo-2-(phenylsulfonyl)-3-nonyl]tetrahydro-3-methyl-2H-pyran-2-acetaldehyde 
• 223693-06-9 (1S,5S,7R,9R,13S,15S,16R)-15-(benzyloxy)-5-[(tert-butyldiphenylsiloxy)methyl]-7-[(p-methoxybenzyl)oxy]-6,6,9,16-tetramethyl-11-(phenylsulfonyl)-4,17-dioxabicyclo[11.3.1]heptadecane-3,10-dione 

Relevant academic research and scientific papers

Stereocontrolled elaboration of natural (-)-polycavernoside A, a powerfully toxic metabolite of the red alga Polycavernosa tsudai

A stereoselective total synthesis of natural levorotatory polycavernoside A (1) has been achieved. Initial investigations produced the properly activated disaccharide unit 18b via the conjoining of building blocks originating from L-fucose and D-xylose. T