223694-98-2Relevant academic research and scientific papers
Synthetic research on cyclitols using C6-chiron, 6-(benzyloxy)-3- cyclohexen-1-ol: A concise and highly diastereoselective synthesis of (-)- gala-quercitol
Maezaki, Naoyoshi,Nagahashi, Noboru,Yoshigami, Ryoko,Iwata, Chuzo,Tanaka, Tetsuaki
, p. 3781 - 3784 (2007/10/03)
Transformation of a C6-chiron, 6-(benzyloxy)-3-cyclohexen-1-ol into polyoxygenated cyclohexanes involving a stereodivergen epoxide rearrangement was investigated. An asymmetric synthesis of (-)-gala-quercitol was accomplished via sequential highly diastereoselective epoxidation, base- promoted epoxide rearrangement, and dihydroxylation.
