223702-36-1Relevant academic research and scientific papers
The first total synthesis of preverecynarmin
Lan, Jiong,Liu, Zuosheng,Cen, Wen,Xing, Yacheng,Li, Yulin
, p. 1963 - 1966 (2007/10/03)
Preverecynaimin, isolated from a pennatulatean coral, has been synthesized from E,E-farnesol.
The first total synthesis of preverecynarmin
Lan, Jiong,Liu, Zuosheng,Li, Yulin,Cen, Wen,Xing, Yacheng
, p. 941 - 946 (2007/10/03)
Preverecynarmin, isolated from a pennatulacean coral, has been synthesized from E,E-famesol. The key steps are alkylation of the cyanohydrin trimethylsilyl ether 5 with the halide 6, the regioselective epoxidation of the siloxyl ether 9, and the intramolecular macrocyclization of the siloxyl ether 12 induced by Ti(0).
