223801-41-0

Basic information

• Product Name: 3-(4-(benzyloxy)-3-methoxyphenyl)-prop-2-enal
• Synonyms: 3-(4-(benzyloxy)-3-methoxyphenyl)-prop-2-enal
• CAS NO: 223801-41-0
• Molecular Weight: 268.312
• Mol File: 223801-41-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-(4-(benzyloxy)-3-methoxyphenyl)-prop-2-enal(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-(benzyloxy)-3-methoxyphenyl)-prop-2-enal(223801-41-0)
• EPA Substance Registry System: 3-(4-(benzyloxy)-3-methoxyphenyl)-prop-2-enal(223801-41-0)

Safety Data

• Hazardous Substances Data: 223801-41-0(Hazardous Substances Data)

Upstream product

• 121-33-5 vanillin 
• 100-39-0 benzyl bromide 

Downstream Products

• 936253-53-1 6-(4-hydroxy-3-methoxyphenyl)hexan-2-one 
• 1330753-47-3 1-(3-bromo-4-methoxyphenyl)-7-(3-methoxy-4-hydroxyphenyl)heptan-3-one 
• 936253-52-0 6-(3-methoxy-4-benzyloxyphenyl)hexa-3,5-dien-2-one 
• 1390642-40-6 (4E,6E)-7-(4-(benzyloxy)-3-methoxyphenyl)-1-(3-bromo-4-isopropoxyphenyl)hepta-4,6-dien-3-one 
• 580-72-3 matairesinol 
• 111194-07-1 (3R,4R)-3,4-bis(4-benzyloxy-3-methoxybenzyl)dihydrofuran-2(3H)-one 
• 1597410-66-6 (Z)-3-(4-(benzyloxy)-3-methoxyphenyl)-2-bromoacrylaldehyde 

Relevant articles and documents

Selective Oxidation of Activated Alcohols by Supported Gold Nanoparticles under an Atmospheric Pressure of O2: Batch and Continuous-Flow Studies

In the hunt for a simple, mild, and scalable protocol for gold nanoparticle-catalyzed oxidation of benzylic and allylic alcohols under O2, we have used commercially available gold nanoparticles supported on alumina to selectively oxidize a large range of activated alcohols to the corresponding carbonyl compounds in good yields (68–99 %) and with excellent selectivity (ca. 100 %). The true heterogeneous nature of the catalysis by gold was demonstrated, allowing us to further adapt this protocol to continuous-flow reactors by using the tube-in-tube technology, in which higher yields were obtained thanks to an improved oxygenation of the reaction medium.

Microwave-assisted synthesis of macrocycles via intramolecular and/or bimolecular Ullmann coupling

Microwave-assisted synthesis of macrocyclic diaryl ethers via intramolecular and/or bimolecular Ullmann coupling is described. Using the optimized conditions, a panel of macrocycles, with different substitution patterns, ring sizes, and linkers, has been successfully synthesized using microwave irradiation. To the best of our knowledge, this work represents the first examples of the microwave-assisted synthesis of macrocyclic diaryl ethers via intramolecular and/or bimolecular Ullmann coupling.