22400-36-8Relevant academic research and scientific papers
THE REACTION OF TETRACHLORO-o-BENZOQUINONE WITH THE SULFIDES OF TRIPHENYLARSINE AND TRIPHENYLSTIBINE
Sidky, M. M.,Mahran, M. R.,Abdou, W. M.
, p. 129 - 136 (2007/10/02)
The reaction of tetrachloro-o-benzoquinone (1) with triphenylarsine sulfide gives a hydrogen-bonded complex of the corresponding hydroquinone and triphenylarsine oxide (5).The same quinone reacts with triphenylstibine sulfide yielding the cyclic adduct (9).In both cases, elemental sulfur is the other product.Possible reaction mechanisms are considered and the structural assignments are based on analytical, chemical and spectroscopic results.
