22416-35-9

Upstream product

• 161955-23-3 (4aR,6S,7R,8S,8aR)-8-Dichloromethyl-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 

Downstream Products

• 42776-09-0 methyl 2-O-acetyl-4,6-O-benzylidene-3-C-methyl-α-D-allopyranoside 
• 79366-15-7 methyl 2,3-di-O-benzyl-4,6-O-benzylidene-3-C-methyl-α-D-allopyranoside 
• 95058-42-7 methyl 6-O-benzyl-2,3-dideoxy-3-C-methyl-α-D-glycero-hex-2-enopyranosid-4-ulose 
• 75843-11-7 Acetic acid (4aR,6S,7R)-6-methoxy-8-methyl-2-phenyl-4,4a,6,7-tetrahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 79366-17-9 methyl 2,3-di-O-benzyl-3-C-methyl-6-O-(p-tolysulfonyl)-α-D-allopyranoside 
• 79366-19-1 methyl 2,3-di-O-benzyl-6-deoxy-3-C-methyl-4-O-(methylsulfonyl)-α-D-allopyranoside 
• 79366-16-8 methyl 2,3-di-O-benzyl-3-C-methyl-α-D-allopyranoside 
• 79366-20-4 methyl 2,3-di-O-benzyl-6-deoxy-3-C-methyl-α-D-ribo-hexopyranosid-4-ulose 
• 79366-18-0 methyl 2,3-di-O-benzyl-6-deoxy-3-C-methyl-α-D-allopyranoside 

Relevant academic research and scientific papers

Reaction of α-Hydroxydichloromethyl Derivatives with Cesium Acetate

The reactions of methyl 4,6-O-benzylidene-2-O-benzoyl- and -2-O-methyl-α-D-ribo-hexopyranosid-3-ulose with dichloromethyllithium gave the corresponding α-hydroxydichloromethyl derivatives in 75percent and 87percent yields respectively.The structures of th