95058-42-7

Upstream product

• 22416-35-9 methyl 4,6-O-benzylidene-3-C-methyl-α-D-allopyranoside 
• 95058-55-2 Toluene-4-sulfonic acid (2R,3R,4R,5R,6S)-2-benzyloxymethyl-4-hydroxy-5,6-dimethoxy-4-methyl-tetrahydro-pyran-3-yl ester 
• 68044-36-0 methyl 4,6-O-benzylidene-3-C-methyl-2-O-methyl-α-D-glucopyranoside 
• 95058-54-1 methyl 6-O-benzyl-3-C-methyl-2-O-methyl-α-D-glucopyranoside 
• 75843-11-7 Acetic acid (4aR,6S,7R)-6-methoxy-8-methyl-2-phenyl-4,4a,6,7-tetrahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 42776-09-0 methyl 2-O-acetyl-4,6-O-benzylidene-3-C-methyl-α-D-allopyranoside 
• 56981-17-0 methyl 2,3-dideoxy-3-C-methyl-α-D-glycero-hex-2-enopyranosid-4-ulose 
• 100-44-7 benzyl chloride 
• 917-54-4 methyllithium 
• 95058-53-0 methyl 3,4-anhydro-6-O-benzyl-3-C-methyl-2-O-methyl-α-D-galactopyranoside 

Relevant academic research and scientific papers

SYNTHESIS OF 2,3-ANHYDRO- AND 3,4-ANHYDRO-HEXOPYRANOSIDES HAVING A METHYL BRANCH ON THE OXIRANE RING, AND THEIR REACTIONS WITH SOME LITHIUM METHYLCUPRATE REAGENTS

Three 2,3-anhydroaldohexopyranosides having a 2-C-methyl or 3-C-methyl branch, as well as three 3,4-anhydroaldohexopyranosides having a 3-C-methyl (7) or 4-C-methyl branch, were newly synthesized.The reactions of these, together with those of a known 3-C-

METHYL 2,3-DIDEOXY-α-D-GLYCERO-HEX-2-ENO-PYRANOSID-4-ULOSE

An efficient synthesis of the title compounds from methyl 4,6-o-benzylidene-α-D-glucopyranoside is described; thus making available a versatile group of intermediates for the syntheses of branched-chain sugars.