22418-73-1

Basic information

• Product Name: 6-methylhept-5-en-2-one oxime
• Synonyms: 6-methylhept-5-en-2-one oxime;6-Methyl-5-hepten-2-one oxime;Einecs 244-984-1
• CAS NO: 22418-73-1
• Molecular Formula: C₈H₁₅NO
• Molecular Weight: 141.2108
• EINECS: 244-984-1
• Mol File: 22418-73-1.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 226.9°C at 760 mmHg
• Flash Point: 124.2°C
• Appearance: /
• Density: 0.87g/cm³
• Vapor Pressure: 0.0289mmHg at 25°C
• Refractive Index: 1.445
• CAS DataBase Reference: 6-methylhept-5-en-2-one oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 6-methylhept-5-en-2-one oxime(22418-73-1)
• EPA Substance Registry System: 6-methylhept-5-en-2-one oxime(22418-73-1)

Safety Data

• Hazardous Substances Data: 22418-73-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C8H15NO/c1-7(2)5-4-6-8(3)9-10/h5,10H,4,6H2,1-3H3

Upstream product

• 110-93-0 6-Methyl-hept-5-en-2-on 
• 106023-79-4 6-Methyl-hept-5-en-2-one O-allyl-oxime 

Downstream Products

• 124920-20-3 2-Isopropyl-5-methyl-1-(toluene-4-sulfonyl)-pyrrolidine 
• 913539-58-9 N-(1,5-dimethylhex-4-en-1-yl)(4-methylphenyl)sulfonamide 
• 69169-53-5 C₁₅H₂₂N₂O₂ 
• 110-93-0 6-Methyl-hept-5-en-2-on 
• 22462-79-9 6-methylhept-5-en-2-amine 

Relevant articles and documents

Dioxime oxalates; new iminyl radical precursors for syntheses of N-heterocycles

Symmetrical and unsymmetrical dioxime oxalates were prepared by treatment of oximes with oxalyl chloride. UV photolysis of these precursors was found to be an atom-efficient way of generating iminyl radicals. The process was most efficient for dioxime oxalates having aryl substituents attached to their C{double bond, long}N bonds. The method was useful for EPR spectroscopic study of iminyl and iminoxyl radicals. Photolyses in toluene solution, of dioxime oxalates containing alkenyl acceptor groups, yielded unsaturated iminyl radicals that ring closed to afford 3,4-dihydro-2H-pyrroles in good yields. Dioxime oxalates with biphenyl substituents also released iminyl radicals that ring closed onto the aromatic acceptor groups and, in acetonitrile solution, this approach provided a useful and atom-efficient method of making substituted phenanthridines.

O-ALLYL ETHER AS A NEW PROTECTIVE GROUP FOR OXIMES AND ITS PALLADIUM-CATALYZED DEPROTECTION.

Oximes are protected by O-allyl ether formation, and their palladium-catalyzed deallylation using triethylammonium formate as a reductant proceeds smoothly in boiling ethanol under mild conditions offering a good protective method for oximes.