Welcome to LookChem.com Sign In|Join Free
  • or

110-93-0

Post Buying Request

110-93-0 Suppliers

Recommended suppliersmore

Product FOB Price Min.Order Supply Ability Supplier
6-Methyl-5-hepten-2-one
Cas No: 110-93-0
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality 6-Methyl-5-Hepten-2-One supplier in China
Cas No: 110-93-0
No Data 1 Metric Ton 30 Metric Ton/Month Simagchem Corporation Contact Supplier
Factory Supply 6-methylhept-5-en-2-one
Cas No: 110-93-0
No Data 1 1 Ality Chemical Corporation Contact Supplier
Amadis Chemical offer CAS#110-93-0;CAT#A894822
Cas No: 110-93-0
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
6-Methyl-5-hepten-2-one
Cas No: 110-93-0
No Data 1 Kilogram Unlimited Kilogram/Day Jiangxi LinQ Spices Co.,Ltd. Contact Supplier
6-methyl-5-hepten-2-one
Cas No: 110-93-0
No Data 1 Metric Ton 1 million Metric Ton/Year COLORCOM LTD. Contact Supplier
6-Methyl-5-hepten-2-one
Cas No: 110-93-0
USD $ 0.9-1.0 / Kilogram 1 Kilogram 1000 Kilogram/Month LIDE PHARMACEUTICALS LIMITED Contact Supplier
Methyl isohexenyl ketone
Cas No: 110-93-0
No Data 1 Kilogram 500 Kilogram/Week Henan Tianfu Chemical Co., Ltd. Contact Supplier
Manufacturer supply CAS 110-93-0 with best quality
Cas No: 110-93-0
USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
110-93-0 5-Hepten-2-one,6-methyl-
Cas No: 110-93-0
USD $ 40.0-50.0 / Gram 1 Gram 1000 Metric Ton/Day WUHAN MULEI NEW MATERIAL CO., LTD Contact Supplier

110-93-0 Usage

Description

6-Methyl-5-hepten-2-one has a strong, fatty, green, citrus-like odor, and a bittersweet taste reminiscent of pear. May be prepared from oil of lemongrass or from citral by refluxing for 12 hours in aqueous solution containing K2C 03, and subsequent distillation and vacuum fractionation; from acetoacetic ester and methylbuten-3-ol-2 with aluminum alcoholate in Carroll’s reaction followed by pyrolysis of the ester.

Uses

Organic synthesis, inexpensive perfumes, fla-voring.

Definition

ChEBI: A heptenone that is hept-5-en-2-one substituted by a methyl group at position 6. It is a volatile oil component of citronella oil, lemon-grass oil and palmarosa oil.

Chemical Properties

6-Methyl-5-hepten-2-one is an important intermediate in the synthesis of terpenoids. Its odor properties are not impressive. It occurs in nature as a degradation product of terpenes. (Z)- and (E)-Tagetone, [3588-18-9], [6752-80-3], are major components of tagetes oil. Solanone [1937-54-8] and pseudoionone [141-10-6] are acyclicC13 ketoneswith a terpenoid skeleton. Solanone is one of the flavor-determining constituents of tobacco, and pseudoionone is an intermediate in the synthesis of ionones.

Chemical Properties

CLEAR SLIGHTLY YELLOW LIQUID

Aroma threshold values

Detection: 50 ppb

Chemical Properties

6-Methyl-5-hepten-2-one has a strong, fatty, green, citrus-like odor and bittersweet taste reminiscent of pear.

Synthesis Reference(s)

Tetrahedron Letters, 28, p. 4893, 1987 DOI: 10.1016/S0040-4039(00)96654-1Synthesis, p. 796, 1981 DOI: 10.1055/s-1981-29599

Preparation

From oil of lemongrass or from citral by refluxing for 12 hours in aqueous solution containing K2CO3, and subsequent distillation and vacuum fractionation; from acetoacetic ester and methyl-buten-3-ol-2 with aluminum alcoholate in Carroll’s reaction followed by pyrolysis of the ester

Occurrence

Originally identified in lemongrass; it has been reported found in the essential oils of palmarosa, lemon, citronella, vervain, geranium, Ocimum canum, Artemisia scoparia, Urtica dioica and others. Also reported found in apple, apricot, sweet and sour cherry, orange juice, citrus peel oils, bilberry, lingonberry, cranberry, guava, grapes, melon, peach, pear, raspberry, strawberry, blackberry, carrot, celery, tomato, potato, clove bud and leaf, ginger, peppermint oil, thymus, Gruyere cheese, butter, beef, hop oil, beer, cognac, cider, white wine, cocoa, tea, peanut oil, avocado, Arctic bramble, cloudberry, olive, passion fruit, plumcot, rose apple, marjoram, starfruit, mango, fig, rice, rice bran, quince, origanum, calamus, buckwheat, corn oil, wort, dried bonito, elderberry, cherimoya, kiwifruit, mountain papaya, endive, lemon balm, clary sage, nectarine, clam, Cape gooseberry, maté, German chamomile oil and mastic gum leaf oil, lime oil and apple brandy

Safety Profile

Moderately toxic by ingestion. A skin irritant. Flammable liquid when exposed to heat, sparks, or flame. When heated to decomposition it emits acrid smoke and irritating fumes.

Taste threshold values

Taste characteristics at 10 ppm: green, vegetative, musty, apple, banana and green bean-like.
InChI:InChI=1/C8H14O/c1-7(2)5-4-6-8(3)9/h5H,4,6H2,1-3H3

110-93-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (A13335)  6-Methyl-5-hepten-2-one, 98%    110-93-0 25g 222.0CNY Detail
Alfa Aesar (A13335)  6-Methyl-5-hepten-2-one, 98%    110-93-0 100g 315.0CNY Detail
Alfa Aesar (A13335)  6-Methyl-5-hepten-2-one, 98%    110-93-0 500g 994.0CNY Detail

110-93-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name sulcatone

1.2 Other means of identification

Product number -
Other names 2-methyl-hept-2-ene-6-one

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:110-93-0 SDS

110-93-0Synthetic route

3,7-dimethyloct-6-en-1-yn-3-ol
29171-20-8

3,7-dimethyloct-6-en-1-yn-3-ol

2-methyl-but-3-yn-2-ol
115-19-5

2-methyl-but-3-yn-2-ol

A

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
potassium hydroxide In water at 93℃; for 6.41667h; Heating / reflux;A 95.2%
B 95.8%
2-methyl-3-buten-2-ol
115-18-4

2-methyl-3-buten-2-ol

2-Methoxypropene
116-11-0

2-Methoxypropene

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With Dimethyl phosphite at 150℃; for 14.6h; Reagent/catalyst; Time; Inert atmosphere;95.1%
hydrogen tris(oxalato)phosphate In methanol at 124.84 - 149.84℃; for 17 - 25h; Product distribution / selectivity;77.3%
hydrogen tris(oxalato)phosphate In acetone at 149.84℃; for 24h; Product distribution / selectivity;56.4%
6-methylhept-5-en-2-one N,N-dimethylhydrazone
74596-83-1

6-methylhept-5-en-2-one N,N-dimethylhydrazone

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With sodium perborate; sodium hydroxide; potassium dihydrogenphosphate; water In tert-butyl alcohol at 60℃; for 24h;94%
3-chloro-3-methyl-1-butene
2190-48-9

3-chloro-3-methyl-1-butene

3,3-dimethyl-allyl chloride
503-60-6

3,3-dimethyl-allyl chloride

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With N,N-dimethyl-formamide; sodium hydroxide In acetone at 50℃; for 2h; Reagent/catalyst; Temperature; Inert atmosphere;92.8%
4-((E)-2,6-Dimethyl-hepta-1,5-dienyl)-morpholine

4-((E)-2,6-Dimethyl-hepta-1,5-dienyl)-morpholine

A

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

B

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With aluminum oxide; potassium permanganate; neutral In acetone for 4h; Ambient temperature;A n/a
B 92%
(E/Z)-3,7-dimethyl-2,6-octadienal
5392-40-5

(E/Z)-3,7-dimethyl-2,6-octadienal

A

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

B

acetaldehyde
75-07-0

acetaldehyde

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydroxide; water at 150℃; for 0.166667h; Microwave irradiation; Green chemistry;A 91%
B n/a
With potassium carbonate
2-methyl-3-buten-2-ol
115-18-4

2-methyl-3-buten-2-ol

acetoacetic acid methyl ester
105-45-3

acetoacetic acid methyl ester

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
90.8%
(E/Z)-3,7-dimethyl-2,6-octadienal
5392-40-5

(E/Z)-3,7-dimethyl-2,6-octadienal

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With pyrrolidine; water In acetonitrile at 20℃; for 12h;90%
With water; potassium carbonate man destilliert mit Wasserdampf und fraktioniert im Vakuum;
With potassium carbonate
C14H26N2O

C14H26N2O

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With selenium(IV) oxide; dihydrogen peroxide In methanol at 20℃; pH=7; aq. phosphate buffer;89%
1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

(E/Z)-3,7-dimethyl-2,6-octadienal
5392-40-5

(E/Z)-3,7-dimethyl-2,6-octadienal

A

2-Methyl-1H-benzimidazole
615-15-6

2-Methyl-1H-benzimidazole

B

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydroxide; water at 150℃; for 0.166667h; Microwave irradiation; Green chemistry;A 61%
B 89%
2-methyl-2-(4-methyl-3-pentenyl)-1,3-dioxolane
3695-38-3

2-methyl-2-(4-methyl-3-pentenyl)-1,3-dioxolane

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With polymer-supported dicyanoketene acetal; water at 20℃; for 20h;88%
With silica gel; toluene-4-sulfonic acid In dichloromethane for 3h;87%
With polymer-supported dicyanoketene acetal; water In acetonitrile at 20℃; for 20h; Hydrolysis;73%
palladium (II) ion In acetone for 1h; Ambient temperature;100 % Chromat.
C10H17NO2

C10H17NO2

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
Stage #1: C10H17NO2 With chromium dichloride; acrylic acid methyl ester In tetrahydrofuran at 25℃;
Stage #2: With water In tetrahydrofuran Further stages.;
88%
2-Methoxypropene
116-11-0

2-Methoxypropene

3-(1-methoxy-1-methyl-ethoxy)-3-methyl-but-1-ene
1196448-62-0

3-(1-methoxy-1-methyl-ethoxy)-3-methyl-but-1-ene

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
Stage #1: 3-(1-methoxy-1-methyl-ethoxy)-3-methyl-but-1-ene at 150℃; for 16h; autoclave;
Stage #2: 2-Methoxypropene; phosphoric acid In acetone at 150℃; for 16h; autoclave;
86%
6-methylhept-5-en-2-ol
4630-06-2, 1569-60-4

6-methylhept-5-en-2-ol

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With trimethylsilyl chromates In dichloromethane at 25℃; for 2h;85%
With butyltriphenylphosphonium dichromate In chloroform for 3.5h; Oxidation; Heating;80%
With [Fe[(S)-N-benzyl-2-phenyl-2-(pyridin-2-ylmethoxy)-N-(pyridin-2-ylmethyl)ethanamine](OTf)2]; dihydrogen peroxide In water; acetonitrile at 20℃; for 2h; Inert atmosphere;69%
6-Methyl-3-(toluene-4-sulfonyl)-hept-5-en-2-one
80868-07-1

6-Methyl-3-(toluene-4-sulfonyl)-hept-5-en-2-one

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With disodium hydrogenphosphate; sodium amalgam In methanol at 0℃; for 2h;85%
4-<(tert-Butyl)dimethylsilyl>-2-methyl-2-(4'-methylpent-3'-enyl)-1,3-dioxole
140458-17-9

4-<(tert-Butyl)dimethylsilyl>-2-methyl-2-(4'-methylpent-3'-enyl)-1,3-dioxole

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With water; oxalic acid Ambient temperature;85%
1,1-dimethylprop-2-enyl 3-oxobutanoate
15973-38-3

1,1-dimethylprop-2-enyl 3-oxobutanoate

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With aluminum oxide at 60℃; for 3h;84%
With aluminum oxide at 60℃; for 3h; Product distribution; substrate supported on Al2O3; Carrol rearrangement of allyl acetoacetates to γ,δ-unsaturated ketones on the surface of chromatographic absorbents;84%
With aluminum isopropoxide at 160℃;
3,7-dimethyloct-6-en-1-yn-3-ol
29171-20-8

3,7-dimethyloct-6-en-1-yn-3-ol

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

A

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

B

(Z)-1-tert-Butylsulfanyl-3,7-dimethyl-octa-1,6-dien-3-ol
86254-75-3

(Z)-1-tert-Butylsulfanyl-3,7-dimethyl-octa-1,6-dien-3-ol

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 50℃; for 6h;A 10%
B 83%
With potassium hydroxide In dimethyl sulfoxide at 50℃; for 6h;A 10%
B 83%
6-methylhept-5-en-2-one oxime
22418-73-1

6-methylhept-5-en-2-one oxime

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With tert.-butylhydroperoxide; dipyridinium dichromate In dichloromethane at 0℃; for 4.5h;80%
2,4-Dimethyl-2-(4'-methylpent-3'-enyl)-1,3-dioxole
140458-18-0

2,4-Dimethyl-2-(4'-methylpent-3'-enyl)-1,3-dioxole

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With hydrogenchloride for 24h;80%
(E/Z)-3,7-dimethyl-2,6-octadienal
5392-40-5

(E/Z)-3,7-dimethyl-2,6-octadienal

A

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

B

4,6-bis(4-methylpent-3-en-1-yl)-6-methylcyclohexa-1,3-diene-1-carbaldehyde
61447-89-0, 474779-14-1

4,6-bis(4-methylpent-3-en-1-yl)-6-methylcyclohexa-1,3-diene-1-carbaldehyde

Conditions
ConditionsYield
With sodium hydride In diethyl ether for 0.5h; Heating;A n/a
B 80%
6-methylhept-5-en-2-ol
4630-06-2, 1569-60-4

6-methylhept-5-en-2-ol

A

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

B

6-methylhept-6-en-2-one
10408-15-8

6-methylhept-6-en-2-one

C

6-methylheptan-2-one
928-68-7

6-methylheptan-2-one

Conditions
ConditionsYield
With reusable unsupported rhenium nanocrystalline particle In neat (no solvent) at 180℃; for 10h; Green chemistry;A 80%
B 5%
C 15%
3-(1-methoxy-1-methyl-ethoxy)-3-methyl-but-1-ene
1196448-62-0

3-(1-methoxy-1-methyl-ethoxy)-3-methyl-but-1-ene

2,2-dimethoxy-propane
77-76-9

2,2-dimethoxy-propane

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
phosphoric acid In acetone at 150℃; for 32h; Product distribution / selectivity; autoclave;78.8%
2,3-epoxygeranial
16996-12-6

2,3-epoxygeranial

A

2-methyl-2-(4-methyl-pent-3-enyl)-oxirane
50340-32-4

2-methyl-2-(4-methyl-pent-3-enyl)-oxirane

B

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In 1,2-dichloro-benzene at 140℃; for 14h; Sealed tube; Inert atmosphere;A 73%
B 23%
tert-butyl acetoacetate
1694-31-1

tert-butyl acetoacetate

2-methyl-3-buten-2-ol
115-18-4

2-methyl-3-buten-2-ol

A

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

B

1,1-dimethylprop-2-enyl 3-oxobutanoate
15973-38-3

1,1-dimethylprop-2-enyl 3-oxobutanoate

Conditions
ConditionsYield
In toluene for 4h; Heating;A 31%
B 72%
1,1-dimethylprop-2-enyl 3-oxobutanoate
15973-38-3

1,1-dimethylprop-2-enyl 3-oxobutanoate

A

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

B

3-methylbut-2-en-1-yl 3-oxobutanoate
21597-32-0

3-methylbut-2-en-1-yl 3-oxobutanoate

Conditions
ConditionsYield
With silica gel at 60℃; for 5h;A n/a
B 70%
5-methyl-4-hexenenitrile
23089-87-4

5-methyl-4-hexenenitrile

methyllithium
917-54-4

methyllithium

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
In diethyl ether at 0℃; for 3h;70%
In diethyl ether at 0℃; for 1h; Methylation;70%
3,7-dimethyloct-6-en-1-yn-3-ol
29171-20-8

3,7-dimethyloct-6-en-1-yn-3-ol

3-tert-Butylsulfanyl-but-3-en-2-ol
86254-77-5

3-tert-Butylsulfanyl-but-3-en-2-ol

A

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

B

(Z)-1-tert-Butylsulfanyl-3,7-dimethyl-octa-1,6-dien-3-ol
86254-75-3

(Z)-1-tert-Butylsulfanyl-3,7-dimethyl-octa-1,6-dien-3-ol

Conditions
ConditionsYield
With potassium hydroxide In neat (no solvent) at 75 - 120℃; for 0.366667h;A 33%
B 64%
2-methyl-3-buten-2-ol
115-18-4

2-methyl-3-buten-2-ol

ethyl acetoacetate
141-97-9

ethyl acetoacetate

A

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

B

3-methylbut-2-en-1-yl 3-oxobutanoate
21597-32-0

3-methylbut-2-en-1-yl 3-oxobutanoate

Conditions
ConditionsYield
In paraffin 1.) 160 deg C, 6 h, 2.) 180 deg C, 3 h;A 60%
B 5%
3-(1-methoxy-1-methyl-ethoxy)-3-methyl-but-1-ene
1196448-62-0

3-(1-methoxy-1-methyl-ethoxy)-3-methyl-but-1-ene

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
Stage #1: 3-(1-methoxy-1-methyl-ethoxy)-3-methyl-but-1-ene at 150℃; for 16h; autoclave;
Stage #2: phosphoric acid In acetone at 150℃; for 16h; autoclave;
60%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

6-methylhept-5-en-2-ol
4630-06-2, 1569-60-4

6-methylhept-5-en-2-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether at 0℃; for 1h;100%
With lithium aluminium tetrahydride In diethyl ether at 0℃; for 1h;99%
With hydrogen; silver trifluoromethanesulfonate; potassium hexamethylsilazane In toluene at 25℃; under 15001.5 Torr; for 24h; Glovebox; chemoselective reaction;99%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

(S)-sulcatol
58917-26-3

(S)-sulcatol

Conditions
ConditionsYield
In isopropyl alcohol at 50℃; for 24h; ADH T. brockii (growing), NADP, PAN 800;100%
With NADH-dependent-formate-dehydrogenase; flavin adenine dinucleotide; NADH at 30℃; for 6h; pH=7.5; aq. buffer; Enzymatic reaction; optical yield given as %ee; enantiospecific reaction;99%
With dichloro(benzene)ruthenium(II) dimer; mono(3-deoxy-3-[N-(2-hydroxyethyl)amino])-β-cyclodextrin; sodium formate In water; N,N-dimethyl-formamide at 50℃; for 12h; optical yield given as %ee; enantioselective reaction;95%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

acetylene
74-86-2

acetylene

3,7-dimethyloct-6-en-1-yn-3-ol
29171-20-8

3,7-dimethyloct-6-en-1-yn-3-ol

Conditions
ConditionsYield
With sodium methylate In methanol at 0 - 5℃; for 0.5h; Inert atmosphere;99.1%
86%
With diethyl ether unter Zusatz von Kaliumhydroxid;
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

6-methylheptan-2-one
928-68-7

6-methylheptan-2-one

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In ethyl acetate under 2280 Torr; for 0.75h; Ambient temperature;99%
With hydrogen In tetrahydrofuran at 24.84℃; under 15001.5 Torr; for 1h;98.2%
With hydrogen; palladium/alumina at 60℃; under 1500.15 Torr; for 66h; Product distribution / selectivity; Autoclave;97.3%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

2-methyl-2,4-di(4-methyl-3-pentenyl)-2,3-dihydro-1H-1,5-benzodiazepine

2-methyl-2,4-di(4-methyl-3-pentenyl)-2,3-dihydro-1H-1,5-benzodiazepine

Conditions
ConditionsYield
With ytterbium(III) triflate at 20℃; for 4h;99%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

ketene t-butyldimethylsilyl methyl acetal
77086-38-5

ketene t-butyldimethylsilyl methyl acetal

methyl 3-((tert-butyldimethylsilyl)oxy)-3,7-dimethyloct-6-enoate

methyl 3-((tert-butyldimethylsilyl)oxy)-3,7-dimethyloct-6-enoate

Conditions
ConditionsYield
Stage #1: 6-Methyl-hept-5-en-2-on With bis(trifluoromethanesulfonyl)amide In diethyl ether at -78 - 23℃; Mukaiyama Aldol Addition; Schlenk technique; Inert atmosphere;
Stage #2: ketene t-butyldimethylsilyl methyl acetal In diethyl ether at -20℃; for 0.5h; Mukaiyama Aldol Addition; Schlenk technique; Inert atmosphere;
99%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

trimethylsulfonium methylsulfate
2181-44-4

trimethylsulfonium methylsulfate

2-methyl-2-(4-methyl-pent-3-enyl)-oxirane
50340-32-4

2-methyl-2-(4-methyl-pent-3-enyl)-oxirane

Conditions
ConditionsYield
With N-benzyl-N,N,N-triethylammonium chloride In dichloromethane98%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

4-methoxy-aniline
104-94-9

4-methoxy-aniline

4-methoxy-N-(6-methylhept-5-en-2-yl)aniline

4-methoxy-N-(6-methylhept-5-en-2-yl)aniline

Conditions
ConditionsYield
With formic acid; chloro-(pentamethylcyclopentadienyl)-{5-methoxy-2-{1-[(4-methoxyphenyl)imino-N]ethyl}phenyl-C}-iridium(lll); triethylamine In methanol at 80℃; for 1h; Inert atmosphere;97%
Vinyl bromide
593-60-2

Vinyl bromide

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

2-bromo-3,7-dimethylocta-1,6-dien-3-ol

2-bromo-3,7-dimethylocta-1,6-dien-3-ol

Conditions
ConditionsYield
Stage #1: Vinyl bromide With n-butyllithium; lithium bromide In tetrahydrofuran; diethyl ether; pentane at -127 - -105℃; for 3h; Inert atmosphere; Schlenk technique;
Stage #2: 6-Methyl-hept-5-en-2-on In tetrahydrofuran; diethyl ether; pentane Inert atmosphere; Schlenk technique;
97%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

vinylmagnesium chloride
3536-96-7

vinylmagnesium chloride

3,7-dimethylocta-1,6-dien-3-ol
78-70-6

3,7-dimethylocta-1,6-dien-3-ol

Conditions
ConditionsYield
With zinc(II) chloride In tetrahydrofuran at 20℃; for 4h; Reagent/catalyst; Solvent; Inert atmosphere; Cooling with ice;96.3%
With tetrahydrofuran
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

ethylene glycol
107-21-1

ethylene glycol

2-methyl-2-(4-methyl-3-pentenyl)-1,3-dioxolane
3695-38-3

2-methyl-2-(4-methyl-3-pentenyl)-1,3-dioxolane

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In benzene Heating;96%
With toluene-4-sulfonic acid In benzene94%
With toluene-4-sulfonic acid In benzene for 5h; Condensation; Heating;92%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

2-propynyl chloride
624-65-7

2-propynyl chloride

4,8-dimethyl-non-7-en-1-yn-4-ol
71869-02-8

4,8-dimethyl-non-7-en-1-yn-4-ol

Conditions
ConditionsYield
With manganese; TiCpCl2 In tetrahydrofuran at 20℃; for 1h; Reagent/catalyst; Inert atmosphere;96%
With 2,4,6-trimethyl-pyridine; bis(cyclopentadienyl)titanium dichloride; manganese; chloro-trimethyl-silane In tetrahydrofuran at 20℃; for 7h; Barbier Coupling Reaction; Inert atmosphere; chemoselective reaction;96%
dimethyltitanocene
1271-66-5

dimethyltitanocene

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

2,6-dimethyl-hepta-1,5-diene
6709-39-3

2,6-dimethyl-hepta-1,5-diene

Conditions
ConditionsYield
Stage #1: dimethyltitanocene; 6-Methyl-hept-5-en-2-on In toluene at 20 - 80℃; for 5h; Inert atmosphere;
Stage #2: With sodium hydrogencarbonate In methanol; water; toluene at 40℃; for 3h; Temperature;
95.3%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

3,7-dimethylocta-1,6-dien-3-ol
78-70-6

3,7-dimethylocta-1,6-dien-3-ol

Conditions
ConditionsYield
With zinc(II) chloride In tetrahydrofuran at 20℃; for 5h; Reagent/catalyst; Solvent; Inert atmosphere; Cooling with ice;95.2%
With tetrahydrofuran; diethyl ether
In tetrahydrofuran at -78℃; Addition;
methyl magnesium iodide
917-64-6

methyl magnesium iodide

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

2,6-dimethylhept-5-en-2-ol
6090-15-9

2,6-dimethylhept-5-en-2-ol

Conditions
ConditionsYield
In diethyl ether for 1h;95%
analog verlaeuft die Reaktion mit Magnesiumaethyljodid;
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

ethyl bromoacetate
105-36-2

ethyl bromoacetate

3-hydroxy-3,7-dimethyl-oct-6-enoic acid ethyl ester
54211-39-1

3-hydroxy-3,7-dimethyl-oct-6-enoic acid ethyl ester

Conditions
ConditionsYield
With zinc In tetrahydrofuran for 2h; Reformatsky Reaction; Reflux;95%
With zinc In tetrahydrofuran for 2h; Reformatsky Reaction; Reflux;95%
With zinc In tetrahydrofuran for 2h; Reformatsky Reaction; Reflux;95%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

6-methylhept-5-en-2-yl trimethylsilyl ether
84569-39-1

6-methylhept-5-en-2-yl trimethylsilyl ether

Conditions
ConditionsYield
With tert-Amyl alcohol; sodium hydride; zinc(II) chloride In tetrahydrofuran for 0.25h; Ambient temperature;95%
Methyl 2-bromopropionate
5445-17-0

Methyl 2-bromopropionate

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

2,3-Dimethyl-3-(4-methyl-pent-3-enyl)-oxirane-2-carboxylic acid methyl ester

2,3-Dimethyl-3-(4-methyl-pent-3-enyl)-oxirane-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran at -78℃;95%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

acetylenemagnesium bromide
4301-14-8

acetylenemagnesium bromide

3,7-dimethyloct-6-en-1-yn-3-ol
29171-20-8

3,7-dimethyloct-6-en-1-yn-3-ol

Conditions
ConditionsYield
In tetrahydrofuran at 0℃; for 1h;95%
In tetrahydrofuran; diethyl ether Grignard reaction;90%
In tetrahydrofuran at -78 - 20℃;87%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

α-halo acetic acid ethyl ester

α-halo acetic acid ethyl ester

3-hydroxy-3,7-dimethyl-oct-6-enoic acid ethyl ester
54211-39-1

3-hydroxy-3,7-dimethyl-oct-6-enoic acid ethyl ester

Conditions
ConditionsYield
With zinc Reformatsky reaction;95%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

C8H14O3

C8H14O3

Conditions
ConditionsYield
With sulfuric acid; dihydrogen peroxide; trifluoroacetic acid In dichloromethane at 0℃; for 6h;95%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

(RS)-6-methylhept-5-en-2-ol

(RS)-6-methylhept-5-en-2-ol

Conditions
ConditionsYield
With methanol; sodium tetrahydroborate at 0 - 35℃;95%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

C12H23NOSi

C12H23NOSi

Conditions
ConditionsYield
Stage #1: 6-Methyl-hept-5-en-2-on With (R,R)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(III) chloride; (tert-Butoxycarbonylmethylene)triphenylphosphorane; Triphenylphosphine oxide In dichloromethane at -30℃; for 0.5h; Inert atmosphere;
Stage #2: trimethylsilyl cyanide In dichloromethane at -30℃; for 20h; Inert atmosphere;
95%
With (R,R)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(III) chloride; ethyl (triphenylphosphoranylidene)acetate In ethyl acetate at -30℃; for 33h; Solvent; Inert atmosphere;92%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

5,6-dihydroxy-6-methyl-heptan-2-one
16194-30-2

5,6-dihydroxy-6-methyl-heptan-2-one

Conditions
ConditionsYield
With osmium(VIII) oxide; 4-methylmorpholine N-oxide In water; acetone; tert-butyl alcohol at 0℃; for 4h;94%
With water; oxygen bei der Sonnenbelichtung;
With potassium permanganate; water
With potassium permanganate
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

N,N-Bis(trimethylsilyl)benzenesulphenamide
17745-52-7

N,N-Bis(trimethylsilyl)benzenesulphenamide

N-<(6-methyl)-5-hepten-2-ylidene>benzenesulfenamide
130485-93-7

N-<(6-methyl)-5-hepten-2-ylidene>benzenesulfenamide

Conditions
ConditionsYield
tetrabutyl ammonium fluoride In tetrahydrofuran at 20℃;94%
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

1,1-dimethylhydrazine
57-14-7

1,1-dimethylhydrazine

6-methylhept-5-en-2-one N,N-dimethylhydrazone
74596-83-1

6-methylhept-5-en-2-one N,N-dimethylhydrazone

Conditions
ConditionsYield
With acetic acid at 20℃; for 3h; Condensation;94%
Yield given;
6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

dimethyl methane phosphonate
756-79-6

dimethyl methane phosphonate

(2-hydroxy-2,6-dimethyl-hept-5-enyl)-phosphonic acid dimethyl ester

(2-hydroxy-2,6-dimethyl-hept-5-enyl)-phosphonic acid dimethyl ester

Conditions
ConditionsYield
Stage #1: dimethyl methane phosphonate With n-butyllithium In tetrahydrofuran; hexane at -70℃; for 0.25h;
Stage #2: 6-Methyl-hept-5-en-2-on In tetrahydrofuran; hexane for 0.0833333h; Further stages.;
94%
Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 110-93-0