224191-95-1Relevant academic research and scientific papers
{FeCp}+-induced hexafunctionalization of hexamethylbenzene with dendrons for the direct synthesis of redox-active iron-centered metallodendrimers
Nlate, Sylvain,Nieto, Yolanda,Blais, Jean-Claude,Ruiz, Jaime,Astruc, Didier
, p. 171 - 176 (2007/10/03)
Phenol tri- and nonaallyl dendrons (3 and 7, respectively) were functionalized at the focal position to give the new triallyl dendrons 4 and 6 and the nonaallyl dendrons 11 and 13 that contain a iodoalkyl or a bromobenzyl termini. All these dendrons were
Activation of aryl ethers and aryl sulfides by the Fe(η5-C5H5)+ group for the synthesis of phenol dendrons and arene-centered poly-olefin dendrimers
Sartor, Valerie,Nlate, Sylvain,Fillaut, Jean-Luc,Djakovitch, Laurent,Moulines, Francoise,Marvaud, Valerie,Neveu, Frederic,Blais, Jean-Claude,Letard, Jean-Francois,Astruc, Didier
, p. 351 - 370 (2007/10/03)
Organo-iron mediated syntheses of dendrons and dendrimers are described. The reaction of [FeCp(η6-p-EtOC6H4Me)][PF6], 1, with Bu(t)OK or KOH and allyl bromide in THF gives both the triallylation of the acidic Me
