22424-65-3

Upstream product

• 95-50-1 1,2-dichloro-benzene 
• 583-53-9 2,3-dibromobenzene 
• 15842-76-9 (2-chloro-phenyl)-trimethyl-silane 
• 17151-09-6 1,2-bis(trimethylsilyl)benzene 

Downstream Products

• 583-55-1 1-Bromo-2-iodobenzene 
• 154318-18-0 tris(o-iodophenyl)silane 
• 154318-17-9 tris(o-trimethylsilylphenyl)silane 
• 19061-38-2 (9s,10s)-9,10-diphenyl-9,10-dihydro-9,10-epoxyanthracene 

Relevant academic research and scientific papers

Copper-Free Double Silylation of 1,2-Dibromobenzenes Using a Mg/LiCl/DMI System

The reaction of 1,2-dibromobenzenes with chlorotrimethylsilane efficiently proceeded in the presence of Mg and LiCl in DMI under mild conditions, giving 1,2-bis(trimethylsilyl)benzenes in good to high yields. The reaction of 1,2-dibromobenzenes with chlorodimethylsilane under the same conditions afforded the corresponding 1,2-bis(dimethylsilyl)benzenes in high yields. Functional group transformations of 1,2-bis(trimethylsilyl)benzene were conducted to demonstrate the synthetic utility.

Tridentate Lewis-acids based on triphenylsilane

Several derivatives of the propeller-shaped ortho-substituted triphenylsilanes, carrying metal- or silicon-based acceptor groups, are reported. They were synthesized starting from tris(2-bromophenyl)fluorosilane, tris(2-vinylphenyl)fluorosilane and tris(2