2244-56-6Relevant academic research and scientific papers
Synthesis and enantioselective hydrogenation of seven-membered cyclic imines: Substituted dibenzo[b,f][1,4]oxazepines
Gao, Kai,Yu, Chang-Bin,Li, Wei,Zhou, Yong-Gui,Zhang, Xumu
, p. 7845 - 7847 (2011/09/13)
Highly enantioselective hydrogenation of seven-membered cyclic imines, substituted dibenzo[b,f][1,4]oxazepines, was achieved, with up to 94% ee, by using the [Ir(COD)Cl]2/(S)-Xyl-C3*-TunePhos complex as the catalyst in the presence of morpholine-HCl.
Novel domino elimination-rearrangement-addition reaction of N-alkoxy(arylmethyl)amines to N-alkyl arylamines
Miyata, Okiko,Ishikawa, Tatsuya,Ueda, Masafumi,Naito, Takeaki
, p. 2219 - 2222 (2007/10/03)
A new domino reaction of N-alkoxy(arylmethyl)amines to N-alkyl arylamines, consisting of three types of reactions: elimination of alcohol, rearrangement of the aryl group, and addition of an organolithium or a magnesium reagent, has been developed for the first time. Georg Thieme Verlag Stuttgart.
