2245-25-2

Basic information

• Product Name: Oxirane, 2-ethyl-2-phenyl-
• CAS NO: 2245-25-2
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Mol File: 2245-25-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Oxirane, 2-ethyl-2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Oxirane, 2-ethyl-2-phenyl-(2245-25-2)
• EPA Substance Registry System: Oxirane, 2-ethyl-2-phenyl-(2245-25-2)

Safety Data

• Hazardous Substances Data: 2245-25-2(Hazardous Substances Data)

Upstream product

• 2039-93-2 1-ethylstyrene 
• 180348-11-2 1-Bromo-2-phenylbutan-2-ol 
• 2181-42-2 trimethylsulphonium iodide 
• 93-55-0 1-phenyl-propan-1-one 
• 1774-47-6 trimethylsulfoxonium iodide 
• 75-11-6 diiodomethane 

Downstream Products

• 5554-71-2 1-diethylamino-2-phenyl-butan-2-ol 
• 60965-66-4 2-Ethyl-2-phenyl-thiiran 
• 106356-54-1 S-2-phenylbutyraldehyde 
• 42307-60-8 (S)-2-methylbutanal 
• 2035-94-1 2-phenylbutan-1-ol 
• 1146490-20-1 C₁₁H₁₄O 
• 886586-59-0 2-Fluoro-2-phenylbutyric acid 
• 20218-42-2 (Z)-but-1-ene-1,2-diyldibenzene 
• 20218-41-1 (E)-but-1-ene-1,2-diyldibenzene 
• 180348-04-3 2-Fluoro-2-phenylbutanol 
• 2439-43-2 (2RS)-2-phenylbutanal 

Relevant articles and documents

Selective Aerobic Oxygenation of Tertiary Allylic Alcohols with Molecular Oxygen

Aerobic epoxidation of tertiary allylic alcohols remains a significant challenge. Reported here is an efficient and highly chemoselective copper-catalyzed epoxidation and semipinacol rearrangement reaction of tertiary allylic alcohols with molecular oxygen. The solvent 1,4-dioxane activates dioxygen, thereby precluding the addition of a sacrificial reductant.

Isomerization of terminal epoxides by a [Pd-H] catalyst: A combined experimental and theoretical mechanistic study

An unusual palladium hydride complex has been shown to be a competent catalyst in the isomerization of a variety of terminal and internal epoxides. The reaction displayed broad scope and synthetic utility. Experimental and theoretical evidence are provided for an unprecedented hydride mechanism characterized by two distinct enantio-determining steps. These results hold promise for the development of an enantioselective variant of the reaction.

An improved preparation of epoxides from carbonyl compounds by using diiodomethane/methyllithium: Synthetic applications

Synthesis of epoxides starting from different carbonyl compounds is easily carried out by using a diiodomethane and methyllithium at 0°C and a short reaction time. Starting from α-aminoaldehydes the reaction affords amino epoxides, with high diastereoselectivity. The products were transformed into 1,3-diaminoalkan-2-ols by treatment with different amines.