224568-48-3Relevant academic research and scientific papers
Competition between novel 8-endo-dig and 6-trig cyclizations of samarium ketyls leading either to benzannulated cyclooctene or to hexahydronaphthalene derivatives
Nandanan, Erathodiyil,Dinesh, Chimmanamada U.,Reissig, Hans-Ulrich
, p. 4267 - 4277 (2007/10/03)
Ketoesters 3a-3h with an alkynylaryl substituent were prepared by standard methods starting from siloxycyclopropanes 6a and 6b. Their reactions with 2.2 equiv. of samarium diiodide in the presence of hexamethyl phosphoramide either produced benzannulated
