2247-00-9Relevant academic research and scientific papers
Stereoselective olefin polymerization catalysts generated by the transfer-epimetalation of olefins or acetylenes with dialkyltitanium(IV) complexes: Three-membered metallocycles as proposed chiral sites
Eisch, John J.,Gitua, John N.
, p. 4172 - 4174 (2003)
Efficient transfer-epimetalations of simple olefins and acetylenes by R2TiL2 reagents (R = Bun, But; L = X) are readily achieved in THF at -78°C to generate titanacyclopropa(e)ne intermediates, readily capable o
