22502-48-3

Basic information

• Product Name: 14-THIOXO-DISPIRO[5.1.5.1]TETRADECAN-7-ONE
• Synonyms: 14-THIOXO-DISPIRO[5.1.5.1]TETRADECAN-7-ONE
• CAS NO: 22502-48-3
• Molecular Formula: C₁₄H₂₀OS
• Molecular Weight: 236.37
• Mol File: 22502-48-3.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 387.7 °C at 760 mmHg
• Flash Point: 188.3 °C
• Appearance: /
• Density: 1.14 g/cm³
• Vapor Pressure: 3.24E-06mmHg at 25°C
• Refractive Index: 1.572
• CAS DataBase Reference: 14-THIOXO-DISPIRO[5.1.5.1]TETRADECAN-7-ONE(CAS DataBase Reference)
• NIST Chemistry Reference: 14-THIOXO-DISPIRO[5.1.5.1]TETRADECAN-7-ONE(22502-48-3)
• EPA Substance Registry System: 14-THIOXO-DISPIRO[5.1.5.1]TETRADECAN-7-ONE(22502-48-3)

Safety Data

• Hazardous Substances Data: 22502-48-3(Hazardous Substances Data)

Usage

General Description

14-THIOXO-DISPIRO[5.1.5.1]TETRADECAN-7-ONE is a complex organic compound with a spirocyclic structure, containing a thioxo group and a ketone functionality. It is a synthetic substance that has potential applications in various fields including pharmaceuticals, agrochemicals, and materials science. The unique structure of 14-THIOXO-DISPIRO[5.1.5.1]TETRADECAN-7-ONE makes it an interesting target for chemical synthesis and exploration of its potential biological and physicochemical properties. Studies on this compound are ongoing to understand its potential uses and effects.

InChI:InChI=1/C14H20OS/c15-11-13(7-3-1-4-8-13)12(16)14(11)9-5-2-6-10-14/h1-10H2

Upstream product

• 950-21-0 dispiro[5.1.5.1]tetradecane-7,14-dione 
• 22502-49-4 Dispiro<5.1.5.1>tetradecane-7,14-dithione 

Downstream Products

• 4630-82-4 methyl cyclohexylcarboxylate 
• 79606-10-3 3-Cyclohexyl-2-thia-spiro[3.5]nonan-1-one 
• 79621-85-5 15-Methoxy-14-oxa-dispiro[5.1.5.2]pentadecane-7-thione 
• 112840-53-6 3-Cyclohexylidene-2-oxa-spiro[3.5]nonane-1-thione 
• 112840-54-7 15-Methoxy-14-thia-dispiro[5.1.5.2]pentadecan-7-one 
• 950-21-0 dispiro[5.1.5.1]tetradecane-7,14-dione 
• 22502-49-4 Dispiro<5.1.5.1>tetradecane-7,14-dithione 
• 79606-09-0 3-Cyclohexylidene-2-thia-spiro[3.5]nonan-1-one 

Relevant articles and documents

Photochemical, Photophysical, and Theoretical Studies on Cyclobutanethiones: α-Cleavage Reactions

Photophysics and photochemistry of cyclobutanethiones 1-5 have been studied with the view to generalize the α-cleavage reactions of cyclobutanethiones.The above cyclobutanethiones possess a unit intersystem crossing efficiency from S1 to T

Thermotropic Liquid Crystals Containing the Dispirotetradecane Unit

Several 3,11-disubstituted dispirotetradecane-7,14-dions were prepared and the cis/trans-isomers were separated.The trans-stereoisomers were converted into the gem-dihalide ketones and mono- and dithioketones.The phase transfer temperatures were

Strain-Assisted α-Cleavage Reactions of Thioketones: Cyclobutanethiones

Photochemical α-cleavage from the lowest triplet state (n?*,T1), resulting in the generation of a diradical intermediate, appears to be general for cyclobutanethiones.The diradical intermediate derived from 1,3-dithione is observed to undergo ring expansion to carbene or close to either dithione or dithiolactone.The photochemical behavior reported here for cyclobutanethiones is different from that of the corresponding cyclobutanones. α-Cleavage processes in the case of cyclobutanethiones are not efficient and are often accompanied by side reactions.