22502-49-4

Usage

InChI:InChI=1/C14H20S2/c15-11-13(7-3-1-4-8-13)12(16)14(11)9-5-2-6-10-14/h1-10H2

Upstream product

• 67-56-1 methanol 
• 22502-50-7 3-cyclohexylidene-2-thia-spiro[3.5]nonane-1-thione 
• 950-21-0 dispiro[5.1.5.1]tetradecane-7,14-dione 
• 22502-48-3 1,4-thioxodispiro[5.1.5⁸.1⁶]tetradecan-7-one 

Downstream Products

• 22502-50-7 3-cyclohexylidene-2-thia-spiro[3.5]nonane-1-thione 
• 80472-67-9 15-Methoxy-14-thia-dispiro[5.1.5.2]pentadecane-7-thione 
• 80472-65-7 14-Thia-dispiro[5.1.5.2]pentadecane-7,15-dithione 
• 107271-47-6 7,14-bis(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dienylidene)dispiro<5.1.5.1>tetradecane 
• 22502-48-3 1,4-thioxodispiro[5.1.5⁸.1⁶]tetradecan-7-one 
• 93097-96-2 C₁₄H₂₀OS₂ 
• 107271-61-4 cyclohexane-1-spiro-1'-<2,4-bis<3,5-di-tert-butyl-4-(trimethylsiloxy)phenyl>bicyclo<1.1.0>butane>-3'-spiro-1''-cyclohexane 

Relevant academic research and scientific papers

Multistep Reversible Redox Systems. 48. 1,3-Bisquinone Methide Cyclobutanes and Related Bicyclobutanes: Syntheses and Redox Properties

A new approach to quinone methides is presented, which starts from diazides and thioketones.Together with some model compounds, 1,3-bisquinone methide cyclobutanes 23, 25, and 37 were synthesized.Reduction with sodium transforms these quinoid compounds in

Strain-Assisted α-Cleavage Reactions of Thioketones: Cyclobutanethiones

Photochemical α-cleavage from the lowest triplet state (n?*,T1), resulting in the generation of a diradical intermediate, appears to be general for cyclobutanethiones.The diradical intermediate derived from 1,3-dithione is observed to undergo ring expansion to carbene or close to either dithione or dithiolactone.The photochemical behavior reported here for cyclobutanethiones is different from that of the corresponding cyclobutanones. α-Cleavage processes in the case of cyclobutanethiones are not efficient and are often accompanied by side reactions.