225088-73-3Relevant academic research and scientific papers
Facile total syntheses of two novel 4-alkenyloxy-2,6- dihydroxyacetophenones
Huang, Chusheng,Zhang, Zhe,Li, Shuhua,Li, Yulin
, p. 148 - 149 (2007/10/03)
Two novel acetophenones, 4-(1'-geranyloxy)-2,6-dihydroxyacetophenone 1 and 4-(1'-farnesyloxy)-2,6-dihydroxyacetophenone 2 isolated from the fruit of Evodia merrillii and from the aerial parts of Borronia ramosa respectively, have been synthesized starting from 2,4,6-trihydroxyacetophenone 3; the key step in their total synthesis is the regioselective alkenylation onto the intermediate 6 with alkenyl bromide.
