225110-92-9Relevant academic research and scientific papers
Simple primary anilines as iminium catalysts for the epoxidation of α-substituted acroleins
Erkkilae, Anniina,Pihko, Petri M.,Clarke, Melanie-Rose
, p. 802 - 806 (2007)
Simple ortho-alkylated anilines have been shown to be excellent iminium catalysts for the epoxidation reaction of α-substituted acroleins. A range of different α-substituted acroleins give the epoxide products in good to excellent yields and good chemoselectivity.
Palladium-Catalyzed Selective Hydrogenolysis of Alkenyloxiranes with Formic Acid. Stereoselectivity and Synthetic Utility
Oshima, Masato,Yamazaki, Hiroyuki,Shimizu, Isao,Nisar, Mohammad,Tsuji, Jiro
, p. 6280 - 6287 (2007/10/02)
Selective hydrogenolysis of alkenyloxiranes to give homoallylic alcohols was carried out using formic acid in the presence of palladium-phosphine catalyst.The selectivity of the reaction depends on a nature and an amount of phosphine ligands.The reaction
