2252-79-1Relevant articles and documents
SYNTHESIS AND REACTIONS OF OXYGEN CONTAINING ORGANOFLUORINE COMPOUNDS. IX. REACTION OF POLYFLUOROALKYL KETONES WITH AMMONIA
Saloutina, L. V.,Zapevalov, A. Ya.,Kolenko, I. P.
, p. 2019 - 2024 (2007/10/02)
The reaction of polyfluoroalkyl ketones with ammonia at reduced temperature was studied.The products from addition of ammonia at the carbonyl group, i.e., geminal amino alkohols, were obtained.If there are chlorine and bromine atoms at the α position, the polyfluoroalkyl ketones dissociate under the influence of ammonia to carboxamides and polyhalogenoalkanes.