22524-46-5

Upstream product

• 4124-41-8 p-toluenesulfonylanhydride 
• 108-94-1 cyclohexanone 

Downstream Products

• 67963-03-5 1-(cyclohex-1-en-1-ylsulfonyl)-4-methylbenzene 
• 254454-34-7 (cyclohex-1-en-1-yl)diphenylphosphine-borane 
• 1884-41-9 1-Cyclohex-1-enyl-3-methoxy-benzene 
• 22618-48-0 1-(cyclohexen-1-yl)-2-methoxybenzene 
• 133039-16-4 2-cyclohexenyl-1,3,5-trimethylbenzene 
• 1293370-58-7 pentyl cyclohex-1-enecarboxylate 
• 1293370-72-5 N-(4-methoxybenzyl)-1-cyclohexene-1-carboxamide 
• 32119-42-9 N-phenylcyclohex-1-enecarboxamide 
• 125378-20-3 1-[(1E)-oct-1-en-1-yl]cyclohexene 
• 1415662-92-8 4-bromo-N-(1-cyclohexenylmethyl)-N-methylbenzenamine 
• 31651-16-8 1-(diethylphosphono)cyclohexene 
• 4922-47-8 1-(phenylthio)cyclohex-1-ene 

Relevant academic research and scientific papers

Coupling of C(sp3)-H bonds with C(sp2)-O electrophiles: mild, general and selective

Herein is reported the mild and general coupling of amine/ether C(sp3)-H bonds with various kinds of C(sp2)-O electrophiles with high selectivity and efficiency. Valuable allylic/benzylic amines are generated in moderate to excellent yields. The utility of this transformation is demonstrated by a broad substrate scope (>50 examples), good functional group tolerance and facile product modification.

Phosphorylation of Alkenyl and Aryl C-O Bonds via Photoredox/Nickel Dual Catalysis

A phosphorylation of alkenyl and aryl C-O bonds at room temperature via photoredox/nickel dual catalysis is reported. By starting from easily available and inexpensive sulfonates, a variety of important alkenyl phosphonates and aryl phosphine oxides are g

Preparation of α,β-unsaturated esters and amides via external-CO-free palladium-catalyzed carbonylation of alkenyl tosylates

Palladium-catalyzed carbonylation of tosylates with phenyl formate is described. This procedure needs neither external carbon monoxide nor any pressure-resistant apparatus. A variety of cyclic and acyclic alkenyl tosylates can be converted into the corresponding phenyl esters in good yields. Furthermore, this method is effective for the one-pot synthesis of α,β-unsaturated amides.

Palladium catalyzed alkoxy- and aminocarbonylation of vinyl tosylates

Chemical equations presented. The palladium catalyzed alkoxycarbonylation and aminocarbonylation of vinyl tosylates are described. A variety of ketone and aldehyde derived vinyl tosylates may be carbonylated in the presence of primary, secondary, and tert

First examples of C-P cross-coupling reaction of vinyl tosylates with diphenylphosphine derivative: New access to vinylphosphine-boranes

Vinylphosphine-borane complexes are efficiently synthesized by palladium-catalyzed CP cross-coupling of vinyl tosylates with diphenylphosphine-borane. Both activated and unactivated vinyl tosylates are successfully used. The vinylphosphine derivatives are

Palladium-catalyzed coupling of vinyl tosylates with arylsulfinate salts

The first palladium-catalyzed coupling of vinyl tosylates with arylsulfinate salts is described. A variety of cyclic and acyclic vinyl tosylates were coupled with aryl sulfinate salts using 2.5 mol % Pd2(dba)3/5.0 mol % XantPhos to g