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O,O-diisobutyl hydrogen dithiophosphate, also known as O,O-diisobutyl phosphorodithioate, is an organophosphorus compound with the chemical formula C8H19O2PS2. It is a colorless to pale yellow liquid with a pungent odor and is used as a pesticide, specifically as an acaricide and miticide, to control mites and ticks in agriculture. The compound is also known by various trade names, such as Kelthane and Flexis. It is effective against a wide range of pests and is known for its low mammalian toxicity, making it a safer option compared to some other pesticides. However, it is important to handle O,O-diisobutyl hydrogen dithiophosphate with care due to its potential environmental impact and the need to follow proper safety protocols to minimize risks to human health and the ecosystem.

2253-52-3

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2253-52-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 2253-52-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,2,5 and 3 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 2253-52:
(6*2)+(5*2)+(4*5)+(3*3)+(2*5)+(1*2)=63
63 % 10 = 3
So 2253-52-3 is a valid CAS Registry Number.
InChI:InChI=1/C8H19O2PS2/c1-7(2)5-9-11(12,13)10-6-8(3)4/h7-8H,5-6H2,1-4H3,(H,12,13)

2253-52-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name Bis(2-methylpropoxy)-sulfanyl-sulfanylidenephosphorane

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2253-52-3 SDS

2253-52-3Upstream product

2253-52-3Relevant academic research and scientific papers

Long-chain alkyl esters of O,O-dialkyl dithiophosphoric and thionophosphoric acids prepared on the basis of red phosphorus, elemental sulfur, alcohols, and industrial fractions of higher monoolefins

Nizamov, Ilyas S.,Shamilov, Radik R.,Salikhov, Ramazan Z.,Nizamov, Ilnar D.,Khodyrev, Yuriy P.,Batyeva, Elvira S.

, p. 484 - 493 (2015/05/20)

Mixtures of long chain S-alkyl O,O-dialkyl dithiophosphates, and O-alkyl O,O-dialkyl thionophosphates were obtained by the reaction of red phosphorus with elemental sulfur, alcohols, and industrial fractions of C16-C18 and C20-C26 of higher olefins in the presence of Lewis acid catalysts. The products obtained possess high anticorrosion activities toward mild steel.

An efficient synthesis of O,O- di propyl (E)-2-[1-methyl 2-oxopropylidene]phosphorohydrazidothiolate (E) oxime and its analogues: A potential marine toxin

Gupta, Arvind K.,Dubey,Parashar,Kaushik

scheme or table, p. 1892 - 1910 (2009/08/07)

An efficient method for the synthesis of Ptychodiscus brevis toxin O,O- di n-propyl (E)-2-[1-methyl 2-oxopropylidene]phosphorohydrazidothiolate (E) oxime (TG-1) and its analogues has been developed using thermally stable and recyclable silica gel and Na2SO4 as a condensing agent and water scavenger, respectively. The compounds were evaluated against fish Rasbora daniconius by determining the LC50 and LC90 values. The results of biological evaluation showed that these compounds have high degree of toxicity. Copyright Taylor & Francis Group, LLC.

Reactivity of epichlorohydrin towards O,O'-dialkyldithiophosphoric acids

Robert, Didier,Curci, Michele,Mieloszynski, Jean-Luc,Paquer, Daniel

, p. 1015 - 1018 (2007/10/02)

The selectivity of the reaction between O,O'-dialkyldithiophosphoric acids and epichlorohydrin is studied by two different methods.New phosphorus triesters are synthesized; they are potential lubricant additives. - Keywords: epichlorohydrin / O,O'-dialkyldithiophosphoric acid / lubricant additive / chlorohydrin

Process for reacting alcohols and/or phenols with phosphorus pentasulfide

-

, (2008/06/13)

The invention relates to a process wherein an alcohol and/or phenol is reacted with phosphorus pentasulfide in the presence of a catalyst which is selected from (a) phosphonium salts of the general formula: STR1 (b) ammonium salts of the general formula: STR2 (c) phosphine oxides of the general formula: STR3 (d) phosphine sulfides of the general formula: STR4 (e) phosphinic acid derivatives of the general formula: STR5 In formulae I through V, the substituents R1, R2, R3 and R4 each stand for identical or different alkyl-, aryl-, alkaryl- or aralkyl- groups having from 1 to 22 carbon atoms. A stands for an inorganic or organic acid, and X and Y, respectively, stand for both oxygen and sulfur, and M stands for a monovalent metal or oxygen.

REDOX REACTIONS OF ANTIMONY(III) O,O-DISUBSTITUTED PHOSPHORODITHIOATES WITH FERRIC CHLORIDE

Woo, Edward J.,Kalbacher, Barbara J.,McEwen, William E.

, p. 269 - 278 (2007/10/02)

The reaction of antimony(III) tris-(O,O-diethylphosphorodithioate) with three equivalents of ferric chloride in ether solution has been found to give ferrous chloride, bis-(O,O-diethylthiophosphoryl) disulfide and dichloroantimony O,O-diethyl phosphorodithioate as the major products.However, a relatively low yield of bis-(O,O-diethylthiophosphoryl) trisulfide was also obtained.The structures of these products were established by independent syntheses.Several additional antimony(III) tris-(O,O-disubstituted phosphorodithioates) were prepared, and the major organic product obtained by reaction of each of these compounds with three equiva lents of ferric chloride was the corresponding bis-(O,O-disubstituted thiophosphoryl) disulfide.A mechanism for this reaction has been suggested, and evidence in support of the mechanism has been presented.The various antimony(III) tris-(O,O-dialkyl phosphorodithioates) are passivating agents in petroleum refining.The results reported in this and in our previous papers indicate that such compounds undergo a variety of reactions with components of crude petroleum prior to the ultimate pyrolysis reactions which occur in the fluid catalytic cracking process.

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