22533-58-0Relevant academic research and scientific papers
Kinetics of Controlled Iodination of Disubstituted Group VIB Metal Carbonyl Derivatives: A Correlative Study
Abdel-Mottaleb, M. S. A.
, p. 590 - 591 (2007/10/02)
Controlled iodination reaction of cis-M(CO)4L2 has been studied spectrophotometrically.The rate constants (kobs) and the activation energy (Ea) of the substitution-oxidation reaction: cis-M0(CO)4L2 + I2 MII(CO)3L2I2 + CO have been determined.Reciprocal relationship between these thermal reactivity parameters and CO stretching wavenumber (νCO) and Cotton-Kraihanzel force constants (CKFC) is observed.
