225642-31-9Relevant academic research and scientific papers
Cp2TiX Complexes for Sustainable Catalysis in Single-Electron Steps
Richrath, Ruben B.,Olyschl?ger, Theresa,Hildebrandt, Sven,Enny, Daniel G.,Fianu, Godfred D.,Flowers, Robert A.,Gans?uer, Andreas
, p. 6371 - 6379 (2018)
We present a combined electrochemical, kinetic, and synthetic study with a novel and easily accessible class of titanocene catalysts for catalysis in single-electron steps. The tailoring of the electronic properties of our Cp2TiX-catalysts that
Mechanism-Based Condition Screening for Sustainable Catalysis in Single-Electron Steps by Cyclic Voltammetry
Liedtke, Theresa,Spannring, Peter,Riccardi, Ludovico,Gans?uer, Andreas
supporting information, p. 5006 - 5010 (2018/03/30)
A cyclic-voltammetry-based screening method for Cp2TiX-catalyzed reactions is introduced. Our mechanism-based approach enables the study of the influence of various additives on the electrochemically generated active catalyst Cp2TiX, which is in equilibrium with catalytically inactive [Cp2TiX2]?. Thioureas and ureas are most efficient in the generation of Cp2TiX in THF. Knowing the precise position of the equilibrium between Cp2TiX and [Cp2TiX2]? allowed us to identify reaction conditions for the bulk electrolysis of Cp2TiX2 complexes and for Cp2TiX-catayzed radical arylations without having to carry out the reactions. Our time- and resource-efficient approach is of general interest for the design of catalytic reactions that proceed in single-electron steps.
Palladium-catalyzed cyclization/cyclopropanation reaction for the synthesis of fused N-containing heterocycles
Nandi, Sukla,Ray, Jayanta K.
scheme or table, p. 6993 - 6997 (2010/02/27)
Palladium-catalyzed cyclization/cyclopropanation can be used to convert a range of substituted cyclic N-aryl allyl/methallyl amines efficiently and selectively to the corresponding fused tetrahydropyridine/cyclopropane-fused isoquinoline derivatives via β
