225660-27-5Relevant academic research and scientific papers
Bimetallic rare-earth/platinum complexes ligated by phosphinoamides
V?lcker, Franziska,Roesky, Peter W.
, p. 9429 - 9435 (2016/07/06)
The heterometallic early-late 5d/4f binuclear phosphinoamido Ln/Pt(0) complexes [(Ph2PNHPh)Pt{μ-(Ph2PNPh)}3Ln(μ-Cl)Li(THF)3] (Ln = Y (1a), Lu (1b)) were obtained by reaction of [Li(THF)4][(Ph2/s
Homoleptic lanthanide complexes of chelating phosphanamides - An experimental and theoretical study
Wetzel, Thomas G.,Dehnen, Stefanie,Roesky, Peter W.
, p. 1086 - 1088 (2007/10/03)
Four chelating ligands are present in the first phosphanamide complexes of Group 3 metals and the lanthanides (see structure shown). However, these ligands coordinate to form a distorted molecular structure. The compounds were characterized by single-crystal X-ray structure analysis and quantum- mechanical investigations with density functional theory and MP2 methods.
