22617-94-3Relevant academic research and scientific papers
The (η6-Naphthalene)(η4-cycloocta-1,5-diene)ruthenium(0) Complex as Precursor for Homogeneous and Heterogeneous Catalysts in the Isomerization of Allyl Ethers and Allyl Acetals to Vinyl Derivatives
Pertici, Paolo,Malanga, Corrado,Giuntoli, Anna,Vitulli, Giovanni,Martra, Gianmarco
, p. 587 - 594 (2007/10/03)
The complex (η6-naphthalene(η4-COD)ruthenium(0), I, (COD=cycloocta-1,5-diene), in the presence of acetonitrile, easily catalyzes the isomerization of allyl ethers and allyl acetals, having different steric and electronic features, to
IRIDIUM PENTAHYDRIDE COMPLEX CATALYZED FORMATION OF C-C BOND BY C-H BOND ACTIVATION FOLLOWED BY OLEFIN INSERTION
Lin, Yingrui,Ma, Dawei,Lu, Xiyan
, p. 3249 - 3252 (2007/10/02)
The formation of carbon-carbon bond was found to occur by first carbon-hydrogen bond activation followed by olefin insertion under the catalysis of an iridium pentahydride complex.
