226253-68-5Relevant academic research and scientific papers
A catalytic enantioselective tandem allylation strategy for rapid terpene construction: Application to the synthesis of pumilaside aglycon
Ferris, Grace E.,Hong, Kai,Roundtree, Ian A.,Morken, James P.
supporting information, p. 2501 - 2504 (2013/03/29)
Catalytic enantioselective 1,2-diboration of 1,3-dienes followed by cascade allylborations with dicarbonyls provides rapid entry into carbocyclic reaction products. The stereochemical course of this reaction was studied along with its application in the synthesis of pumilaside aglycon.
Synthesis of cyclopentenones 2- and 2,4-oxygenated from furfural
E Silva, Natalia R. Da. F.,De Magalhaes, Gouvan C.
, p. 1477 - 1483 (2007/10/03)
2-Benzyloxy-4-methoxy-2-cyclopentenone and 2-benzyloxy-2-cyclopentenone were efficiently prepared using furfuryl alcohol as the starting material. The synthetic route employed in both cases involves the previous preparation of a ketoaldehyde that is subsequently cyclized to the parent cyclopentenone. Each stage of this route involves reactions of very low cost, with simple synthetic procedures and very good yields.
