22627-01-6

Upstream product

• 529-19-1 2-Methylbenzonitrile 
• 95-46-5 2-methylphenyl bromide 

Downstream Products

• 1018-97-9 2,2'-dimethylbenzophenone 
• 246853-44-1 2,2'-dimethylbenzhydrylamine 
• 39265-29-7 N-(2-Dimethylaminoethyl)-2,2'-dimethyl-diphenylketoimin 
• 39265-31-1 N-(2-Diethylaminoethyl)-2,2'-dimethyl-diphenylketoimin 
• 39267-91-9 N-(4-Dimethylaminobutyl)-2,2'-dimethyl-diphenylketoimin 
• 22978-49-0 2-methyl-N-(2-methylphenyl)benzamide 
• 29041-25-6 2,2'-bis(bromomethyl)benzophenone 
• 39265-35-5 N-(3-Dimethylaminopropyl)-2,2'-dimethyl-diphenylketoimin 

Relevant academic research and scientific papers

A Diastereodivergent and Enantioselective Approach to syn- And anti-Diamines: Development of 2-Azatrienes for Cu-Catalyzed Reductive Couplings with Imines That Furnish Allylic Amines

We introduce a new reagent class, 2-azatrienes, as a platform for catalytic enantioselective synthesis of allylic amines. Herein, we demonstrate their promise by a diastereodivergent synthesis of syn- and anti-1,2-diamines through their Cu-bis(phosphine)-catalyzed reductive couplings with imines. With Ph-BPE as the supporting ligand, anti-diamines are obtained (up to 91% yield, >20:1 dr, and >99:1 er), and with the rarely utilized t-Bu-BDPP, syn-diamines are generated (up to 76% yield, 1:>20 dr, and 97:3 er).

Pd-catalyzed enantioselective C-H iodination: Asymmetric synthesis of chiral diarylmethylamines

An enantioselective C-H iodination reaction using a mono-N-benzoyl- protected amino acid has been developed for the synthesis of chiral diarylmethylamines. The reaction uses iodine as the sole oxidant and proceeds at ambient temperature and under air.