22653-07-2

Upstream product

• 486-25-9 9-fluorenone 
• 92-66-0 4-bromo-1,1'-biphenyl 

Downstream Products

• 17165-86-5 9-([1,1′-biphenyl]-4-yl)-9H-fluorene 
• 6321-77-3 9-Chlor-9-(3-phenyl-phenyl)-fluoren 
• 95820-64-7 9-p-Biphenylyl-9-brom-fluoren 
• 22653-09-4 ethyl-(9-biphenyl-4-yl-fluoren-9-yl)-ether 

Relevant academic research and scientific papers

Compounds using fluorene as core, preparation method of compounds and application of compounds in organic light emission diode device

The invention relates to organic compounds using fluorene as a core, a preparation method of the compounds and an application of the compounds in an organic light emission diode (OLED) device. The compounds have a following structure: the fluorene is connected with a dibenzo five-membered ring and ring structure through a carbon-carbon bond, the carbon-carbon bond connection not only improves the chemical stability of the material, but also avoids exposure of active positions of a branched chain group, and the whole molecule is a larger rigid structure and has a higher triplet state energy level (T1); the compounds have large steric hindrance, are not easy to rotate, and have a more stable stereoscopic space structure, so that the compounds have a higher glass transition temperature and molecular thermal stability; in addition, HOMO and LUMO distribution positions of the compounds are separated from each other, so that the compounds have suitable HOMO and LUMO energy levels; therefore, the compounds can effectively improve the luminous efficiency and the service life of the device after being applied to the OLED device.

Organic compound taking fluorene as core and application of organic compound

The invention relates to an organic compound taking fluorene as a core and application of the organic compound in an OLED (Organic Light Emission Diodes) device. The compound is of a structure that the fluorene is connected with a dibenzo five-membered ri

Organic compound with fluorene as nucleus and application of same to OLED device

The invention relates to an organic compound with fluorene as a nucleus and application of the same to an OLED device. The compound is such structured that fluorine is connected with a benzo six-membered ring via a C-C bond; connection via the C-C bond is beneficial for improving the chemical stability of the compound and preventing active positions of branched groups from exposure; the whole molecule is of a large rigid structure, has a high triplet-state energy level (T1) and is large in steric hindrance and not prone to rotation, so the three-dimensional spatial structure of the compound is more stable; and thus, the compound has a high glass transition temperature and molecular heat stability. Moreover, the HOMO and LUMO of the compound are distributed at different positions, so the compound has appropriate HOMO and LUMO energy levels. Thus, the compound can effectively improve the luminescence efficiency and service life of the OLED device when applied to the device.

Flash photolysis study of a Friedel-Crafts alkylation. Reaction of the photogenerated 9-fluorenyl cation with aromatic compounds

A combination of flash photolysis and product analysis is employed to investigate the reaction of aromatic compounds (ArH) with the 9-fluorenyl cation (Fl+) photogenerated from 9-fluorenol in 1,1,1,3,3,3-hexafluoroisopropyl alcohol (HFIP).The availability of the photochemical route to Fl+ means that the reaction of benzylic-type cation with ArH can be directly followed by flash photolysis.An additional feature with electron-rich ArH is that the cyclohexadienyl cation is observed to grow as Fl+ decays.Thus both cationic intermediates of a Friedel-Crafts alkylation are observed in the same experiment.The formation of the cyclohexadienyl cation is demonstrated to be reversible, or at least quasi-reversible, with the kinetic analysis furnishing absolute rate constants for the formation of this cation as well as for its loss of H+ and Fl+.Values of kH:kD for benzene:benzene and toluene:toluene are ca. 1.5 and demonstrate that Fl+ addition is at least partly reversible with these compounds as well.The Hammett ρ+ value obtained for a series of the less electron-rich ArH is -8, indicative of a transition state with considerable cyclohexadienyl cation character.Anisole shows a negative deviation from from Hammett correlation line, explained by the addition of Fl+ to ArH becoming encounter-controlled.This behaviour is dramatically illustrated in a comparison of data for Fl+ and Br2.For the less electron-rich ArH, rate constants for the two electrophiles are parallel.However, from m-xylene through pentamethylbenzene, the rate with Fl+ is unchanged, while the rate with Br2 increases over 1000-fold.The concept of encounter control with Fl+ is strongly supported by the absolute rate constants, which for the electron-rich ArH are all in the range 1-2 E9 dm3 mol-1 s-1, a magnitude typical of diffusion-controlled reactions.The electron-rich ArH also show no intermolecular selectivity since their reactions are encounter-controlled, but have a high intramolecular selectivity.It is suggested that a factor influencing the latter is the reversibility of formation of the cyclohexadienyl cation from the encounter complex.

Versatile and Convenient Lattice Hosts derived from Singly Bridged Triarylmethane Frameworks, X-Ray Crystal Structures of Three Inclusion Compounds

A new family of host molecules, based on the singly bridged triarylmethanol and triarylacetic acid frameworks, is described.These hosts form crystalline inclusions with a variety of uncharged organic molecules ranging from protic dipolar to apolar compounds (130 different species).The formation and stoicheiometry depend in a systematic manner on structural parameters of the host, such as the nature of the functional group and the substituents, and on the substituent positions.The crystal structures of three inclusion compounds have been studied by X-ray diffraction.They reveal the building principles of the new inclusion family.In the crystals of 1a*benzene (8:3), the benzene is interstitially entrapped by H-bonded tetramer clusters of 1a.Crystals of 1a*dioxane (4:3) are built of H-bonded 2:1 host-guest complexes including interstitial molecules of dioxane.In the case of 4c*EtOH (1:1), the building principle is formation of 2:2 host-guest clusters via a twelve-membered H-bonded ring.