Cas 226546-08-3,(3R,6S,8aS)-6-Allyl-6-[(R)-1-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-2,2,8a-trimethyl-3-phenyl-hexahydro-oxazolo[3,2-a]pyridine-5-thione

226546-08-3

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Basic information

Product Name: (3R,6S,8aS)-6-Allyl-6-[(R)-1-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-2,2,8a-trimethyl-3-phenyl-hexahydro-oxazolo[3,2-a]pyridine-5-thione
Synonyms: (3R,6S,8aS)-6-Allyl-6-[(R)-1-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-2,2,8a-trimethyl-3-phenyl-hexahydro-oxazolo[3,2-a]pyridine-5-thione
CAS NO:226546-08-3
Molecular Formula:
Molecular Weight: 623.975
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (3R,6S,8aS)-6-Allyl-6-[(R)-1-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-2,2,8a-trimethyl-3-phenyl-hexahydro-oxazolo[3,2-a]pyridine-5-thione(CAS DataBase Reference)
NIST Chemistry Reference: (3R,6S,8aS)-6-Allyl-6-[(R)-1-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-2,2,8a-trimethyl-3-phenyl-hexahydro-oxazolo[3,2-a]pyridine-5-thione(226546-08-3)
EPA Substance Registry System: (3R,6S,8aS)-6-Allyl-6-[(R)-1-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-2,2,8a-trimethyl-3-phenyl-hexahydro-oxazolo[3,2-a]pyridine-5-thione(226546-08-3)

Safety Data

Hazard Codes: N/A
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Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 226546-08-3(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 226546-08-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,2,6,5,4 and 6 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 226546-08:
(8*2)+(7*2)+(6*6)+(5*5)+(4*4)+(3*6)+(2*0)+(1*8)=133
133 % 10 = 3
So 226546-08-3 is a valid CAS Registry Number.

226546-08-3Upstream product

226546-08-3Downstream Products

226546-08-3Relevant academic research and scientific papers

An asymmetric route to novel chiral cyclohexenones with spiro-connected cyclopentenes. Further utility of chiral bicyclic thiolactams and the [3,3] thio-Claisen products

Lemieux,Devine,Mechelke,Meyers

, p. 3585 - 3591 (2007/10/03)

Sequential allylation of chiral, nonracemic thiolactam 8 affords clean thio-Claisen [3,3] products 11. The stereoselectivity of the rearrangement was found to be on the order of 10-11:1, with the exo-endo products responsible for the mixture. Addition of hydride or methyllithium-cerium chloride gave clean addition to the thiolactam in the form of its iminium salts 12. Hydrolysis gave 4,4-dialkylcyclohexenones 15, which were cyclized to the cyclopentene derivatives 16 using Grubbs' catalyst.

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