22685-99-0

Upstream product

• 20790-88-9 IrHCl₂(CO)(P(CH₃)2C₆H₅)2 
• 124-41-4 sodium methylate 
• 73191-02-3 (tetrabutylammonium)[IrCl₂(CO)2] 
• 672-66-2 Dimethyl(phenyl)phosphine 

Downstream Products

• 17595-26-5 IrHCl₂(CO)(P(CH₃)2(C₆H₅))2 
• 77059-30-4 [IrCl₃(CO)(P(CH₃)2C₆H₅)2] 
• 36713-96-9 trans-carbonylchlorobis(dimethylphenylphosphine)rhodium 
• 77018-07-6 [IrCl₃(CO)(P(C₂H₅)2C₆H₅)(P(CH₃)2C₆H₅)] 
• 77018-06-5 trans-[IrCl(CO)(PEt₂Ph)(PMe₂Ph)] 
• 15842-03-2 trans-IrCl(CO){PC₆H₅(C₂H₅)2} 
• 20792-55-6 IrClBr(CO)(P(CH₃)2C₆H₅)2(CH₂CHCH₂) 
• 23319-79-1 IrClBr(CO)(P(CH₃)2C₆H₅)2(CH₂CHCH₂) 
• 20756-25-6 allylcarbonyldichlorobis(dimethylphenylphosphine)iridium(III) 
• 103191-32-8 IrClI(CH(CH₃)CH₂CH₃)(CO)(P(CH₃)2C₆H₅)2 
• 103191-28-2 IrClI(CH₂CH₃)(CO)(P(CH₃)2C₆H₅)2 
• 103191-29-3 IrClI(CH₂CH₂CH₃)(CO)(P(CH₃)2C₆H₅)2 
• 22606-11-7 IrICl(CH₃)(CO)(P(CH₃)2C₆H₅)2 
• 22606-07-1 IrCl₂(CH₃)(CO)(P(CH₃)2C₆H₅)2 

Relevant academic research and scientific papers

A high-yield synthetic approach to trans-[Ir(ER3)2(CO)X] (ER3=PMe3, PEt3, PPhMe2, PPh2Me, P(OMe)3, AsMe3, AsEt3, AsPh3, SbPh3; X=Cl, Br)

The complex [Ir(CO)2X2][NBu4] (X=Cl, Br) forms Vaska-type complexes, trans-[Ir(ER3)2(CO)X], when treated with two equivalents of aryl- or alkyl-phosphines, arsines, or stibines under a CO atmosphere. The synthesis is general for a wide range of phosphines, arsines, or stibines irrespective of the cone angle. For small cone-angle ligands, the initial addition of ligand to [Ir(CO)2X2][NBu4] is performed at low temperature. The synthesis and characterisation of three new Vaska-type complexes trans-[Ir(P(OMe)3)2(CO)Cl], trans-[Ir(AsMe3)2(CO)Cl], and trans-[Ir(AsEt3)2(CO)Cl] is also reported. Elsevier Science Ltd.